Home | Links | Contact Us | More About Intellectual Property | Bookmark
Search patents:
Home Adhesives and Rubbers Optically-non-linear-active-waveguiding-material-comprising-donor-and-acceptor-groups-containing-triphenylcarbinols

 Process for extrusion
We claim: 1. A process for the co-extrusion of an inner layer around a conductive medium and an ...


 Ethylene-.alpha.-olefin copolymer and composition, and film, laminate and electrical insulating material comprising same
An object of the present invention to provide an ethylene-.alpha.-olefin copolymer excellent in ...


 Thermoplastic elastomeric blend of monoolefin copolymer rubber, amorphous polypropylene resin and crystalline polyolefin resin
I claim: 1. A thermoplastic elastomer which is a blend of: A. a monoolefin copolymer rubber which ...


 Olefine thermoplastic elastomer sheet
OF THE INVENTION The present invention is described in more detail. First, the olefin ...


 Odor free polylactic acid modified aqueous emulsion paints free of volatile coalescing organic solvent
OF THE INVENTION The air dry emulsion latex paint of this invention comprises a film forming ...


 Coextruded chewing gum containing a soft non-SBR gum core portion
What is claimed is: 1. A coextruded chewing gum having a soft gum center portion, comprising an ...


 Aqueous dispersion of polymer composition
We claim: 1. An aqueous dispersion of a polymer composition comprising (A) a copolymer which ...


 Thermoplastic polymer blends comprising EPDM and EP
The thermoplastic polymer blends of this invention comprise a physical mixture of two polymer ...


 Viscosity index improver and method for producing the same
OF THE INVENTION The olefinic polymers to be used in this invention as component (1) are generally ...


 Alkyd resins and coating compositions therefrom based on copolymers of allyl alcohol propoxylates and vinyl aromatic monomers
OF THE INVENTION The copolymers of the invention have recurring units of a vinyl aromatic monomer ...


 Optically non-linear active waveguiding material comprising donor and acceptor groups-containing triphenylcarbinols

Details
Inventors: Engbersen, Johannes F. J.; Kelderman, Erik; Reinhoudt, David N.; Verboom, Willem;
Assignee: Akzo Nobel NV (Arnhem, NL)
Primary Examiner: Michl; Paul R.
Assistant Examiner: Asinovsky; Olga
Attorney, Agent or Firm: Fennelly; Richard P., Morris; Louis A.

The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a donor group and acceptor group-containing triphenylcarbinol as a dopant. Said dopants have a high hyperpolarizability and have a charge-transfer absorption band which is about the same as that of their corresponding compounds having only one donor-.pi.-acceptor unit. The triphenylcarbinols were found to display good solubility in polymers. Nitro-functionalized triphenylcarbinols are preferred because of their charge-transfer absorption band at a low wavelength (.lambda..sub.max at about 290 nm). Aldehyde-functionalized calix(4)arenes were also found to have this low wavelength charge-transfer absorption band (.lambda..sub.max at about 270 nm). Triphenyls comprising stilbene donor-.pi.-acceptor units are preferred because of their high hyperpolarizability.

DETAILED DESCRIPTION We claim: 1.
An optically non-linear active waveguiding material comprising an optically transparent polymer and an optically non-linear active dopant comprising a donor-.
pi.
-acceptor unit, characterised in that the optically non-linear active dopant is a donor and acceptor groups-containing triphenylcarbinol.
2.
An optically non-linear active waveguiding material according to claim 1, characterised in that the donor and acceptor groups-containing triphenylcarbinol satisfies Formula 1: ##STR4## wherein: R.
sup.
1 stands for --O-alkyl having 1-30 carbon atoms, --O-aryl having 1-30 carbon atoms, --NH.
sub.
2, --NHR.
sup.
4, --NR.
sup.
4 R.
sup.
4, --NHCOR.
sup.
4, --OH, .
sub.
-- O.
sup.
--, --SH, --S.
sup.
--, SR.
sup.
4, --OCOR.
sup.
4, --F, --Cl, --I, --Br, --R.
sup.
4, --R.
sup.
5, R.
sup.
2 stands for --NO.
sub.
2, --CN, --R.
sup.
4 COOH, --R.
sup.
5 COOH, --R.
sup.
4 COONa, --R.
sup.
5 COONa, --COOR.
sup.
4, --COOR.
sup.
5, --CONH.
sub.
2, --CONHR.
sup.
4, --CONR.
sup.
4 R.
sup.
4, --CONHR.
sup.
5, --R.
sup.
5, an aldehyde group having 1-30 carbon atoms, a ketone group having 1-30 carbon atoms, --SO.
sub.
2 R.
sup.
4, --SO.
sub.
2 OR.
sup.
4, --SO.
sub.
2 R.
sup.
5, --SO.
sub.
2 OR.
sup.
5, --CH.
dbd.
CH--C.
sub.
6 H.
sub.
4 --NO.
sub.
2, --CH.
dbd.
CH--C.
sub.
6 R.
sup.
4 H.
sub.
3 --NO.
sub.
2, --CH.
dbd.
CH--C.
sub.
6 H.
sub.
4 --CN, --CH.
dbd.
CH--C.
sub.
6 R.
sup.
4 H.
sub.
3 --CN, --CH.
dbd.
CH--C.
sub.
6 H.
sub.
4 --SO.
sub.
2, --CH.
dbd.
CH--C.
sub.
6 R.
sup.
4 H.
sub.
3 --SO.
sub.
2, --CH.
dbd.
CH--C.
sub.
6 H.
sub.
4 --SO.
sub.
2 O, --CH.
dbd.
CH--C.
sub.
6 R.
sup.
4 H.
sub.
3 --SO.
sub.
2 O, R.
sup.
3 stands for --H or --CH.
sub.
3, R.
sup.
4 represents an alkyl group having 1-30 carbon atoms, R.
sup.
5 represents an aryl group having 1-30 carbon atoms, R.
sup.
6 represents --H or an alkyl group having 1-3 carbon atoms.
3.
An optically non-linear active waveguiding material according to claim 2, characterised in that the donor and acceptor groups-containing triphenylcarbinol satisfies Formula 2: ##STR5## wherein: R.
sup.
1 stands for --O-alkyl having 1-30 carbon atoms, --O-aryl having 1-30 carbon atoms, --NH



Related patents
  High melt strength, propylene polymer, process for making it, and use thereof
This invention in one aspect comprises a normally solid, high molecular weight, non-linear, substantially gel-free, propylene polymer material, the molecular chains of ...
  Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers
Thermoplastic compositions formed of olefinic, polymer blends and which have superior physical properties and adherence for coating materials such as paints are ...
  Impact modified thinwall polymer compositions
Modified compositions useful in thinwall thermoforming and molding applications have now been discovered to have a good balance of high flowability, good impact ...
  Acrylic sheet having uniform distribution of coloring and mineral filler before and after thermoforming
OF THE INVENTION Referring to FIG. 1A, the recommended (DuPont Corian Technical Bulletin CTDC-110, October, 1987) minimum bending radius of three inches for a prior art ...
  Flow formable composites having polymodal fiber distributions
OF THE INVENTION The process of this invention involves (1) an aqueous medium, preferably (2) a binder, usually at least partially in the form of a latex which contains ...
  Transceiver site selection a cellular communications system
The various features of the invention will now be described with respect to the figures, in which like parts are identified with the same reference characters. R...
  Edge strengthened substrate of a data storage disk and method for fabricating same
The present invention is an edge strengthened substrate of a data storage disk and a method for fabricating same. A strengthening agent is preferably applied to selected ...
  Thermoplastic olefin resin composition and laminated film or sheet thereof
What we claim is: 1. A thermoplastic olefin resin composition composed of a blend of (i) 5 to 95% by weight, based on the weight of the blend, of a random copolymer ...
  Blends of a propylene/.alpha.-olefin copolymer with isotactic prolypropylene
According to this invention there is provided a composition consisting essentially of a blend of an elastomeric copolymer of 45-90 mole percent of propylene and 10-55 ...
  Acrylic multilayer polymer powder
In light of these circumstances, the present inventors studied the structures of coagulated powders of relatively rigid acrylic multilayer polymers, and with a melt-...

0.674

Archive: All patents - Links

Copyright (c)2006 Eipa-patents.org - All rights reserved