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Process for producing telechelic, branched and star thermoplastic resin polymers |
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Release agent composition
| Details |
Inventors: Ishikawa, Hiroki; Naganawa, Tsutomu; Ona, Isao;
Assignee: Dow Corning Toray Silicon Co., Ltd. (Tokyo, JP)
Primary Examiner: Marquis; Melvyn I.
Assistant Examiner: Dean; Karen A.
Attorney, Agent or Firm: Spector; Robert
The release agent compositions of the present invention comprise mixtures of amino-functional and amine-free polydimethylsiloxanes wherein the viscosity, amine equivalent and content of dimethylsiloxane oligomers containing up to 20 silicon atoms are within specified limits. The compositions do not evolve oily volatiles or silicon dioxide powder even during exposure to elevated temperatures. |
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DETAILED DESCRIPTION OF THE INVENTION The objectives of this invention are achieved by release agent composition comprising a mixture of (A) an amino-functional diorganopolysiloxane that contains no more than 50,000 ppm Si. sub. . ltoreq. 20 dimethylsiloxane oligomer and (B) an amine-free dimethylpolysiloxane that contains no more than 500 ppm Si. sub. . ltoreq. 20 dimethylsiloxane oligomer, wherein said composition has an amine equivalent weight of from 1,000 to 150,000, a Si. sub. . ltoreq. 20 dimethylsiloxane oligomer content not exceeding 5,000 ppm, and a viscosity of 50 to 30,000 centistokes at 25. degree. C. The amino-functional diorganopolysiloxane, referred to hereinafter as ingredient A, forms the basis of the present release agents and can be represented by the general formula ##STR1## In this formula R. sup. 1 represents a monovalent hydrocarbon radical, and is exemplified by but not limited to C. sub. 1 to C. sub. 20 monovalent hydrocarbon radicals such as methyl, ethyl, propyl, butyl, pentyl, vinyl, 3,3,3-trifluoropropyl, and phenyl. The R. sup. 1 groups in a molecule need not all be identical. R. sup. 1 is most typically methyl, however combinations of methyl with other hydrocarbon radicals is also typically used for R. sup. 1. Preferably at least one of the R. sup. 1 substituents on each silicon atom is methyl. R. sup. 2 represents the hydrogen atom or a monovalent hydrocarbon radical that is exemplified by but not limited to methyl, ethyl, propyl, phenyl, and cyclohexyl. The group represented by A is a monovalent hydrocarbon radical as defined for R. sup. 1 or an organic group with the formula ##STR2## where a is an integer with a value of zero to 10 and it is generally zero or 1 and Q represents a divalent hydrocarbon radical, and it is exemplified by but not limited to alkylene such as ##STR3## and alkarylene such as --(CH. sub. 2). sub. 2 C. sub. 6 H. sub. 4 --. Q is most preferably propylene, m and n are both integers with values of at least 1, and the sum m+n is equivalent to a viscosity at 25. degree. C
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