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 Stable free radical polymerization processes and compositions thereof

Details
Inventors: Kazmaier, Peter M.; Keoshkerian, Barkev; Loutfy, Rafik O.; Moffat, Karen A.; Georges, Michael K.; Hamer, Gordon K.; Veregin, Richard P. N.;
Assignee: Xerox Corporation (Stamford, CT)
Primary Examiner: Berman; Susan W.
Assistant Examiner:
Attorney, Agent or Firm: Palazzo; E. O.

A free radical polymerization process for the preparation of polymer comprising: a first heating and photoinitiating with ultraviolet light of a mixture comprised of a stable free radical agent, and at least one polymerizable monomer compound; optionally cooling said mixture; a second heating of said mixture at a temperature of from about 100.degree. C. to about 160.degree. C.; isolating the polymer product formed; and optionally washing and drying said polymer.

DETAILED DESCRIPTION What is claimed is: 1.
A free radical polymerization process for the preparation of polymer having a narrow polydispersity from about 1.
05 to about 1.
95 comprising; photoinitiating with ultraviolet (UV) light in the presence of a first heating of a mixture comprised of a stable free radical agent, and at least one polymerizable monomer compound, and wherein said first heating is at a temperature of from about a -40.
degree.
C.
to about 110.
degree.
C.
; cooling said mixture; a second heating of said mixture at a temperature of from about 100.
degree.
C.
to about 160.
degree.
C.
; isolating the polymer product formed; and optionally washing and drying said polymer.
2.
A process in accordance with claim 1 wherein said first heating is at a temperature of from about a minus 20.
degree.
C.
to about 60.
degree.
C.
3.
A process in accordance with claim 2 wherein said second heating is at a temperature of from about 120.
degree.
C.
about 160.
degree.
C.
4.
A process in accordance with claim 2 wherein the resin product is isolated by precipitation in a nonsolvent, followed by filtration.
5.
A process in accordance with claim 1 wherein said first heating is at a temperature of about 25.
degree.
C.
6.
A process in accordance with claim 1 wherein said second heating is at a temperature of from about 120.
degree.
C.
about 160.
degree.
C.
7.
A process in accordance with claim 1 wherein said at least one polymerizable monomer compound is from 1 polymerizable monomer compound to about 5 different kinds of polymerizable monomer compounds.
8.
A process in accordance with claim 1 wherein said polymerizable monomer is styrene.
9.
A process in accordance with claim 1 further including adding a photoinitiator component prior to or during said first heating.
10.
A process in accordance with claim 9 wherein said photoinitiator component is selected from the group consisting of benzoin, disulfide, aralkyl ketone, oximinoketone, peroxy ketone, acyl phosphine oxide, and diamino ketone.
11.
A process in accordance with claim 9 wherein said photoinitiator component is 1-hydroxycyclohexyl phenyl ketone



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