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Details
Inventors: Frey, Hans-Helmut; Klug, Helmut;
Assignee: Hoechst Aktiengesellschaft (Frankfurt am Main, DE)
Primary Examiner: Seccuro; Carman J.
Assistant Examiner:
Attorney, Agent or Firm: Connolly and Hutz

Blends of vinyl chloride polymers and chlorination products of polyolefins well suitable for dry blend technique are obtained by using a chlorinated low pressure polyethylene with a chlorine content of 38 to 42% by weight, a residue value of 55 to 70% by weight and a swelling value of less than 1% by weight, prepared from high-density polyethylene, having a density of 0.955 to 0.965 g/cm.sup.3, a melting index of 20 to 65 g/10 min and a reduced specific viscosity of 1 to 2 dl/g, under certain conditions.

DETAILED DESCRIPTION What is claimed is: 1.
Thermoplastic composition consisting of (a) 95 to 70% by weight of a vinyl chloride polymer and (b) 5 to 30% by weight of a chlorinated high-density polyethylene, wherein the chlorinated high-density polyethylene has a chlorine content of 38 to 42% by weight, a residue value of 55 to 70% by weight (determined by extraction with toluene/acetone in a ratio of 1:1) and a swelling value of less than 1% by weight (measured in methyl-cyclohexane) and has been prepared from high-density polyethylene having a density of 0.
955 to 0.
965 g/cm.
sup.
3, a melting index MFI 190/5 (DIN 53 735) of 20 to 65 g/10 min.
and a reduced specific viscosity (ISO/R 1191) of 1 to 2 dl/g, by chlorinating in water or hydrochloric acid in the presence of 0 to 2% by weight of silicic acid and 0 to 1% by weight of siloxane oil, each time calculated on the high-density polyethylene used, at temperatures of from 50 to 120.
degree.
C.
, while introducing at least the last 10% of chlorine at a temperature of from 110.
degree.
to 120.
degree.
C.
2.
Thermoplastic composition as claimed in claim 1, the high-density polyethylene whereof has been prepared at a temperature of from 110.
degree.
to 120.
degree.
C.
3.
Thermoplastic composition as claimed in claim 1, the high-density polyethylene whereof has been chlorinated at a temperature beginning in the range of from 70.
degree.
to 90.
degree.
C.
and ending in the range of from 110.
degree.
to 120.
degree.
C.
4.
Process for preparing a thermoplastic composition by mixing (a) 95 to 70% by weight of a vinyl chloride polymer ans (b) 5 to 30% by weight of a chlorinated high-density polyethylene wherein there is used a chlorinated high-density polyethylene that has a chlorine content of 38 to 42% by weight, a residue value of 55 to 70% by weight (determined by extraction with toluene/acetone in a ratio of 1:1) and a swelling value of less than 1% by weight (measured in methylcyclohexane) and that has been prepared from a high-density polyethylene having a density of 0



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