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 Thermoplastic elastomer composition

Details
Inventors: Hikasa, Tadashi; Ibuki, Koichiro; Hamanaka, Tatsuo; Fukuyama, Masahiro;
Assignee: Sumitomo Chemical Company, Limited (Osaka, JP)
Primary Examiner: Securro; Carman J.
Assistant Examiner:
Attorney, Agent or Firm: Cushman, Darby & Cushman

The present invention provides a thermoplastic elastomer composition excellent in oil resistance. This composition comprises a partially crosslinked mixture of (A) an ethylene copolymer rubber comprising ethylene and an acrylate ester or a methacrylate ester and (B) an olefin polymer and, if necessary, (C) an olefin copolymer rubber.

DETAILED DESCRIPTION We claim: 1.
A thermoplastic elastomer composition which comprises a partially crosslinked mixture of (A) an ethylene copolymer rubber comprising ethylene and an acrylate ester or a methacrylate ester, at least one olefin polymer selected from a polypropylene and a propylene/.
alpha.
-olefin copolymer, and (C) an .
alpha.
-olefin copolymer rubber which is either (i) ethylene.
alpha.
- olefin copolymer rubber or (ii) ethylene.
alpha.
-olefin/nonconjugated diene copolymer rubber, wherein molar ratio of said ethylene to said acrylate ester of methacrylate ester in the ethylene copolymer rubber (A) is 50-85:50:15.
2.
A composition according to claim 1 wherein content of ethylene copolymer rubber (A) is 5-90% by weight, that of olefin polymer (B) is 5-60% by weight and that of olefin copolymer rubber (C) is 5-85% by weight.
3.
A composition according to claim 1 wherein the ethylene copolymer rubber (A) additionally contains at least one of unsaturated glycidyl ester, acid anhydride and unsaturated compound containing carboxylic acid group.
4.
A composition according to claim 1 wherein the ethylene copolymer rubber (A) additionally contains other comonomers copolymerizable with ethylene.
5.
A composition according to claim 1 wherein the olefin copolymer rubber (C) is an ethylene-propylene-non-conjugated diene rubber.
6.
A composition according to claim 1 wherein the olefin copolymer rubber (C) is an oil-extended olefin copolymer rubber containing 150 parts by weight or less of a mineral oil type softening agent per 100 parts by weight of the olefin copolymer rubber.
7.
A process for producing a thermoplastic elastomer composition which comprises mixing (A) an ethylene copolymer rubber comprising ethylene and an acrylate ester or a methacrylate ester, (B) at least one olefin polymer selected from a polypropylene and a propylene.
alpha.
-olefin copolymer, and (C) an olefin copolymer rubber which is either (i) ethylene.
alpha.
-olefin copolymer rubber or (ii) ethylene.
alpha.
-olefin/nonconjugated diene copolymer rubber and an organic peroxide, and dynamically heat-treating the mixture, wherein molar ratio of said ethylene to said acrylatae ester or methacrylate ester in the ethylene copolymer ruber (a) is 50-85:50-15



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