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Home Adhesives and Rubbers Water-curable-silane-modified-alkylene-alkyl-acrylate-copolymers-and-a-process-for-the-production-thereof

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 Water-curable, silane modified alkylene-alkyl acrylate copolymers and a process for the production thereof

Details
Inventors: Keogh, Michael J.;
Assignee: Union Carbide Corporation (Danbury, CT)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

Water-curable silane modified alkylene-alkyl acrylate copolymers, produced by reacting an alkylene-alkyl acrylate copolymer with a polysiloxane in the presence of an organo titanate, which are useful as extrudates about wires and cables.

DETAILED DESCRIPTION What is claimed is: 1.
A water-curable silane modified alkylene-alkyl acrylate copolymer which is the reaction product of an alkylene-alkyl acrylate copolymer and a polysiloxane having the formula: ##STR19## wherein R is a hydrocarbon radical or an oxy substituted hydrocarbon radical, R.
sup.
1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of at least 2; said polysiloxane derived from a mixture of different silanes having the formula: ##STR20## wherein the variables are as previously defined.
2.
A silane modified alkylene-alkyl acrylate copolymer as defined in claim 1 wherein the polysiloxane is derived from a mixture of acetooxyethyltrimethoxy silane and .
gamma.
methacryloxypropyltrimethoxy silane.
3.
A silane modified alkylene-alkyl acrylate copolymer as defined in claim 1 wherein the alkylene-alkyl acrylate copolymer is an ethylene-ethyl acrylate copolymer.
4.
A silane modified alkylene-alkyl acrylate copolymer as defined in claim 1 wherein the polysiloxane has the formula: ##STR21## wherein R is an alkylene radical having one to 18 carbon atoms inclusive, R.
sup.
1 is an alkyl radical having one to 18 carbon atoms inclusive or an alkylene radical having 2 to 18 carbon atoms inclusive, each V is an alkoxy radical having one to 18 carbon atoms inclusive, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of 5 to 25 inclusive; said polysiloxane derived from a mixture of different silanes having the formula: ##STR22## wherein the variables are as previously defined.
5.
A silane modified alkylene-alkyl acrylate copolymer as defined in claim 4 wherein the alkylene-alkyl acrylate copolymer is an ethylene-ethyl acrylate copolymer.
6.
A silane modified alkylene-alkyl acrylate copolymer as defined in claim 1 wherein the polysiloxane is derived from a mixture of silanes containing acetooxyethyltrimethoxy silane



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