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Method for recovering uncrosslinked synthetic resin waste
| Details |
Inventors: Takayanagi, Yasuyuki; Endoh, Satoshi; Sugama, Naoki; Sugita, Masaru;
Assignee: Nitto Chemical Industry Co., Ltd. (Tokyo, JP)
Primary Examiner: Spear; Frank
Assistant Examiner:
Attorney, Agent or Firm: Sughrue, Mion, Zinn, Macpeak & Seas
A method for recovering an uncrosslinked synthetic resin waste including dissolving the uncrosslinked synthetic resin waste in a solvent containing, as an active ingredient, one or more oxyisobutyric acid esters selected from an alkyl .alpha.-alkoxyisobutyrate, an alkyl .beta.-alkoxyisobutyrate and an alkyl .alpha.-hydroxyisobutyrate. This invention provides a method for recovering a plastic waste by using a highly safe solvent which is free from the problems encountered in the conventional methods with the use of aromatic hydrocarbons or halogenated hydrocarbons, and comprises non-halogen solvents, forms no substance causing environmental problems, has a high ability to dissolve plastic wastes, has neither toxicity nor any offensive odor, is not accumulated in nature because of its high biodegradability, and has a relatively high boiling point. |
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DETAILED DESCRIPTION OF THE INVENTION It is an important point that the solvent used in the method for recovering an uncrosslinked synthetic resin waste of the present invention contains an alkyl oxyisobutyrate. Examples of the oxyisobutyric acid ester include alkyl . alpha. -alkoxyisobutyrates (corresponding to formula (1)), such as methyl . alpha. -methoxyisobutyrate, ethyl . alpha. -methoxyisobutyrate, methyl . alpha. -ethoxyisobutyrate and ethyl . alpha. -ethoxyisobutyrate; alkyl . beta. -alkoxyisobutyrates (corresponding to formula (2)), such as methyl . beta. -methoxyisobutyrate, ethyl . beta. -methoxyisobutyrate, methyl . beta. -ethoxyisobutyrate and ethyl . beta. -ethoxyisobutyrate; and alkyl . alpha. -hydroxyisobutyrates (corresponding to formula (3)), such as methyl . alpha. -hydroxyisobutyrate and ethyl . alpha. -hydroxyisobutyrate. Taking dissolving power and volatility into consideration, it is particularly preferable to use methyl . alpha. -methoxyisobutyrate, methyl . beta. -methoxyisobutyrate, methyl . beta. -ethoxyisobutyrate or methyl . alpha. -hydroxyisobutyrate. Moreover, these oxyisobutyrates are excellent in safety. In particular, methyl . beta. -methoxyisobutyrate and methyl . alpha. -hydroxyisobutyrate are highly safe compounds, each having an acute toxicity LD. sub. 50 of not less than 5,000 mg/kg (in the case of oral administration to rat). The alkyl . alpha. -alkoxyisobutyrates (corresponding to formula (1)), alkyl . beta. -alkoxyisobutyrates (corresponding to formula (2)) and alkyl . alpha. -hydroxyisobutyrates (corresponding to formula (3)) may be used either individually or in combination of two or more thereof. The mixing ratio thereof may be arbitrarily selected. These oxyisobutyric acid esters represented by formulae (1), (2) and (3) are available as disclosed, for example, in EP-A-429800. The alkyl . alpha. -alkoxyisobutyrates, alkyl . beta. -alkoxyisobutyrates and alkyl . alpha. -hydroxyisobutyrates used in the present invention are highly compatible with other general organic solvents, for example, alcohols, esters, ketones, amides and aromatic hydrocarbons
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