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 High molecular weight collagen-like protein polymers
What is claimed is: 1. An unnatural collagen-like polymer of at least about 30 kD, characterized by:...


 Compositions and processes employing activators for the generation of peroxyacids

Details
Inventors: Sanderson, William R.;
Assignee: Interox Chemicals Limited (London, GB2)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

Hydrogen peroxide and persalt washing or disinfecting compositions perform comparatively ineffectively at ambient to low operating temperatures. More effective washing/disinfection processes are obtained by employing according to the instant invention there with a peroxyacid generator selected from compounds having the general formula (I): ##STR1## in which R.sub.1 and R.sub.2 and R.sub.3 often are hydrogen, R.sub.6 is often hydrogen or methyl and R.sub.4 and R.sub.5 are often methyl or phenyl. R.sub.3 or R.sub.5 can each also represent a difunctional group terminating at its other end in a second gem-diester group or in an enol ester group. Especially preferred peroxyacid generators include 1,1,5-triacetoxypent-4-ene, 1,1,5,5-tetraacetoxy pentane, the corresponding butene and butane compounds, ethylidene benzoate acetate and bis(ethylidene acetate) adipate.

DETAILED DESCRIPTION I claim: 1.
A process for the generation of a peroxyacid species comprising the step of bringing into contact hydrogen peroxide or an adduct thereof or some other compound which develops hydrogen peroxide, with a peroxyacid generator having the general formula (I) ##STR9## in which R.
sub.
1 R.
sub.
2 and R.
sup.
6 are each selected from hydrogen and lower alkyl groups, and R.
sub.
3 is selected from hydrogen, lower alkyl and aryl groups and groups of formula (II) or (III) ##STR10## in which R.
sub.
7 represents a carbon-carbon bond or an alkylene diradical, R.
sub.
4 and R.
sub.
5 each represent hydrogen or a lower alkyl, or an aryl, aralkyl or alkaryl group and R.
sub.
5 can also be a from group of formula (IV) --R.
sub.
8 --CO--O--R.
sub.
9 in which R.
sub.
8 represents an alkylene diradical and R.
sub.
9 represents a vinyl or alkyl substituted vinyl group or group of formula (V) ##STR11## 2.
A composition comprising (a) hydrogen peroxide or an adduct thereof or a compound which develops hydrogen peroxide and (b) a peroxyacid generator having the general formula (I) as described in claim 1.
3.
A composition according to claim 2 in which R.
sub.
1 and R.
sub.
2 in Formula I each represent hydrogen and R.
sub.
3 and R.
sub.
6 each represent hydrogen or a lower alkyl group.
4.
A composition according to claim 2 in which R.
sub.
3 represents a group of formula II or III in which R.
sub.
7 represents a diradical comprising 1, 2 or 3 linear carbon atoms, unsubstituted or further substituted by one or more C.
sub.
1 -C.
sub.
4 alkyl groups.
5.
A composition according to claim 4 in which R.
sub.
1, R.
sub.
2 and R.
sub.
6 represent hydrogen.
6.
A composition according to claim 2 in which R.
sub.
4 represents hydrogen or a lower alkyl or phenyl or substituted phenyl group.
7.
A composition according to claim 2 in which R.
sub.
5 represents a lower alkyl or phenyl or substituted phenyl group.
8.
A composition according to claim 2 in which R.
sub.
5 represents an alkylene diradical containing from 2 to 10 linear carbon atoms, unsubstituted or substituted by one or more C



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