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Home Electrical and Wave Oxygen-absorbing-resin-composition-containing-water-absorbing-polymer-olefin-resin-and-oxygen-scavenger

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 Oxygen-absorbing resin composition containing water-absorbing polymer, olefin resin and oxygen scavenger

Details
Inventors: Koyama, Masayasu; Oda, Yasuhiro; Yamada, Muneki;
Assignee: Toyo Seikan Kaisha Ltd. (Tokyo, JP)
Primary Examiner: Michl; Paul R.
Assistant Examiner: Rajguru; U. K.
Attorney, Agent or Firm: Sughrue, Mion, Zinn, Macpeak & Seas

Disclosed is an oxygen-absorbing resin composition valuable for preserving water-containing contents such as drinks and precooked food, which comprises a heat-formable resin or resin composition having an oxygen permeation coefficient larger than 10.sup.-12 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg at a temperature of 20.degree. C. and a relative humidity of 0% and a water adsorption of at least 1% in pure water at 20.degree. C., and an oxygen scavenger incorporated into said resin or resin composition, and a laminate, a liner, a cap and a vessel, which are formed by using this oxygen-absorbing resin composition.

DETAILED DESCRIPTION In the above-mentioned oxygen-absorbing resin composition used in the conventional technique, since the resin per se has a large oxygen permeation coefficient, it is expected that the oxygen-absorbing speed is probably high.
However, the oxygen-absorbing speed is much lower than the oxygen-absorbing speed attained in the case where a paper-packaged oxygen-absorbing agent is directly charged, and the oxygen-absorbing effect is not satisfactory.
It is therefore a primary object of the present invention to provide a heat-formable oxygen-absorbing resin composition having a high oxygen-absorbing speed and an excellent oxygen-absorbing capacity.
Another object of the present invention is to provide a cap or packaging vessel formed by using the above resin composition, which is valuable for preserving water-containing contents such as drinks and precooked foods and is excellent in the sanitary effect because oxygen in the interior is promptly absorbed or permeation of oxygen from the outside is effectively cut.
In accordance with the present invention, there is provided an oxygen-absorbing resin composition comprising a heat-formable resin or resin composition having an oxygen permeation coefficient larger than 10.
sup.
-12 cc.
multidot.
cm/cm.
sup.
2 .
multidot.
sec.
multidot.
cmHg at a temperature of 20.
degree.
C.
and a relative humidity of 0% and a water adsorption of at least 1% in pure water at 20.
degree.
C.
, and an oxygen scavenger incorporated into said resin or resin composition.
The heat-formable resin used in the present invention is a blend of an olefin resin with a water-absorbing resin.
More specifically, it is a blend of a polymer selected from the group consisting of a modified polyethylene oxide, a vinyl alcohol polymer, a sodium acrylate polymer and an acrylic acid/vinyl alcohol copolymer with an olefin resin.
An advantage of using such a polymer blend in the present invention is set forth below.
In order to sufficiently enable the effectiveness of the oxygen scavenger blended in the resin composition, it is necessary to add an oxygen-absorbing agent to a resin having a sufficiently large oxygen permeation coefficient and water retention



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