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Home Electrical and Wave Use-of-certain-polyphenylene-oxides-for-the-production-of-aromatic-block-polyether-poly-ester-carbonates-by-the-interfacial-process

 Use of certain polyphenylene oxides for the production of aromatic block polyether-poly(ester) carbonates by the interfacial process

Details
Inventors: Freitag, Dieter; Bottenbruch, Ludwig; Wilms, Klaus G.; Tacke, Peter;
Assignee: Bayer Aktiengesellschaft (Bayerwerk, DE)
Primary Examiner: Phynes; Lucille M.
Assistant Examiner:
Attorney, Agent or Firm: Harsh; Gene, Gil; Joseph C., Preis; Aron

This invention relates to the use of polyphenylene oxides corresponding to the following general formula: ##STR1## for the production of aromatic block polyether-poly(ester) carbonates by the interfacial process and also to the block polyether-poly(ester) carbonates obtainable by the process.

DETAILED DESCRIPTION We claim: 1.
A process for the production of an aromatic block polyether-poly(ester) carbonate which comprises interfacial process for producing poly(ester) carbonates using a polyphenylene oxide corresponding to the following general formula: ##STR10## wherein R independently represents hydrogen or C.
sub.
1 -C.
sub.
4 alkyl; X represents ##STR11## wherein R is as defined above, --O--, --S-- or --SO.
sub.
2 --; and m and n independently represent integers of from 1 to 200.
2.
A process as claimed in claim 1 wherein there are used (1) one or more hydroxyl group-containing polyphenylene oxides; (2) one or more other diphenols; (3) one or more chain-terminators; (4) phosgene; optionally (5) up to 80 mole %, based on the total moles of carbonate and carboxylate groups, of one or more arylene dicarboxylic acid dichlorides; and, optionally, (6) from 0.
01 to 1 mole %, based on moles of diphenols (1) and (2), of one or more branching agents; one or more polyphenylene oxides as defined in claim 1 being used as component (1) in quantities of from 5 to 95%, by weight, based on the total weight of the resulting block polyether-poly(ester) carbonate.
3.
A process as claimed in claim 2, wherein from 10 to 95%, by weight, of polyphenylene oxide (I) is used.
4.
A process as claimed in claim 3 wherein from 20 to 60%, by weight, of polyphenylene oxide (I) is used.
5.
A process as claimed in claim 2, wherein polyphenylene oxide (I) having a number average molecular weight (Mn) of from 600 to 10,000 is used.
6.
A process as claimed in claim 5 wherein polyphenylene oxide (I) having Mn as value of from 900 to 3000 is used.
7.
A process as claimed in claim 5 wherein polyphenylene oxide (I), wherein m and n independently represent integers of from 3 to 20, is used.
8.
A process as claimed in claim 2, wherein polyphenylene oxide (I), wherein R represents CH.
sub.
3, is used.
9.
A process as claimed in claim 2, wherein the catalyst required for the interfacial method is added after the phosgene and the arylene dicarboxylic acid dichloride



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