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Details
Inventors: Markin, Trevor Leslie; Bones, Roger John; Scott, Keith Taylor; May, Geoffrey John; Robinson, Graham;
Assignee: Chloride Silent Power Limited (London, GB2)
Primary Examiner: Skapars; Anthony
Assistant Examiner:
Attorney, Agent or Firm: Beveridge, DeGrandi, Kline & Lunsford

In a sodium-sulphur cell having a solid electrolyte separating sodium from a cathodic region containing sulphur/polysulphides in a graphite felt, a cathode current collector is formed of an aluminium substrate on which is an interstrate layer of nickel-chromium alloy covered by a coating of titanium oxide or other electronically conductive oxide intrinsically inert to the cathodic reactant.

DETAILED DESCRIPTION It is one of the objects of the present invention to provide an improved form of cathode current collector for use in sodium-sulphur cells.
According to the present invention, in a sodium-sulphur cell having a solid electrolyte separating sodium forming the anode from a cathodic reactant comprising sulphur/polysulphides, there is provided a cathode current collector comprising an aluminum substrate with, over the surface of the substrate exposed to the cathodic reactant, an interstrate layer of a nickel-chromium alloy as hereinafter defined, and an outer coating over the interstrate layer of a plasma-sprayed or detonation-gun sprayed electronically conductive oxide inert with respect to the cathodic reactant.
Plasma-spraying techniques using a plasma-arc gun are well-known.
For applying the oxide coating, it is possible to use plasma-spraying or a detonation gun (D-gun) coating process.
This latter process operates by metering oxygen, acetylene and coating material into a firing chamber.
There are detonated by a spark to produce a hot (3300.
degree.
C), high speed 750 m/s gas stream which forces the particles against the substrate.
The advantages of the process are the good quality of the bond between coating and substrate and the ability to keep the substrate relatively cool (<150.
degree.
C) which avoids distortion or metallurgical changes.
Plasma-spraying by contrast has a higher temperature (.
about.
17000.
degree.
C) but lower particle velocities.
The nickel-chromium alloy may be a binary alloy of nickel or chromium but, more generally, it is an alloy containing at least 50% by weight of nickel and chromium together, each of these components comprising at least 10% by weight of the material, the major constituents, if any, apart from nickel and chromium, being iron and/or cobalt and possibly with minor proportions of one or more of the following materials; molybdenum, tungsten, niobium, aluminium, titanium, manganese, carbon and yttrium, the minor constituents totalling not more than 5% by weight



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