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 Fluid catalytic cracking catalyst

Details
Inventors: Petty, Randall H.; Bartley, Burton H.;
Assignee: Texaco Inc. (White Plains, NY)
Primary Examiner: Shine; W. J.
Assistant Examiner:
Attorney, Agent or Firm: Ries; Carl G., Kulason; Robert A.

An active alumina composite and a cracking catalyst comprising the composite useful in hydrocarbon conversion processes. The composite and catalyst are particularly useful in fluid catalytic cracking processes, wherein sulfur-containing feedstock is subjected to catalytic conversion at a temperature in the range of about 800.degree. F. to about 1300.degree. F. in the presence of the catalyst which becomes sulfided during the conversion reaction and thereafter the catalyst is subjected to regeneration by burning sulfur-containing coke from the catalyst with an oxygen-containing gas at a temperature within the range of about 800.degree. to 1500.degree. F. The novel catalyst composition comprises 90 to 99 weight percent cracking catalyst and 1 to 10 weight percent of a composite of alumina and bismuth oxides containing 0.05 to 25 weight percent bismuth, calculated as the metal. This catalyst composition has the ability to remove sulfur oxides from gases to a greater extent than catalyst compositions comprising cracking catalyst and active alumina. The composition may comprise also platinum or a platinum group metal as a carbon monoxide combustion promoter.

DETAILED DESCRIPTION We claim: 1.
A composition of matter as a component in catalytic cracking compositions which consists essentially of a composite of active alumina and 0.
5 to 1 weight percent bismuth as bismuth oxide prepared by forming a cogel of active alumina and a soluble bismuth salt, drying said gel and calcining the resulting composite at a temperature in the range of 1000.
degree.
to 1200.
degree.
F.
for at least one hour.
2.
A composition according to claim 1 wherein said composite contains from 0.
1 to 10 weight percent bismuth.
3.
A composition according to claim 1 wherein said composite contains from 0.
1 to 4 weight percent bismuth.
4.
A catalytic cracking catalyst composition comprising a major portion of a cracking catalyst composed of a crystalline zeolite in a supporting matrix in intimate admixture with a minor portion of a composite of bismuth oxide and active alumina, wherein said composite contains from 0.
05 to 25 weight percent bismuth, calculated as the metal.
5.
A catalytic cracking catalyst according to claim 4 wherein said composition contains 90 weight percent of said cracking catalyst and 10 weight percent of said composite of active alumina and bismuth oxides.
6.
A catalytic cracking catalyst according to claim 5 wherein said composite of bismuth oxide and alumina contains from 0.
1 to 4 weight percent bismuth.
7.
A catalytic cracking catalyst according to claim 5 wherein said composite contains 0.
5 to 1 weight percent bismuth.
8.
A catalytic cracking catalyst according to claim 4 wherein the cracking catalyst composition comprises platinum or a platinum compound.
9.
A composition of matter as a component in catalytic cracking compositions consisting essentially of alumina and bismuth and containing 0.
05 to 25 weight percent bismuth prepared by forming a cojel of alumina and a soluble bismuth salt, drying the gel and calcining the resulting composite at a temperature in the range of 1000.
degree.
to 1200.
degree.
F.
for at least one hour.
10.
A composition of matter according to claim 9 wherein said cojel is prepared by dissolving alumina in a nitric acid solution of bismuth nitrate



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