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 Fuel cell electrolyte supply system and apparatus

Details
Inventors: Struthers, Ralph C.;
Assignee:
Primary Examiner: LeFevour; Charles F.
Assistant Examiner:
Attorney, Agent or Firm: Maxwell; Georges A.

A system and apparatus for supplying and circulating fresh electrolyte to and through the anode and ion exchange sections of a plurality of related air/metal fuel cells; preventing the flow of shunt currents through the electrolyte between the fuel cell sections; removing heat produced by fuel cell reaction from the electrolyte; removing solid byproducts of fuel cell reaction from the electrolyte; and reconstituting spent electrolyte. The system and apparatus commingles electrolyte with a hydrophobic liquid dielectric which has a specific gravity which is less than the specific gravity of the electrolyte and conducting the commingled liquids through small diameter conductors of dielectric material to the fuel cell sections. The liquid dielectric in the electrolytes and conductors maintain a current path in the electrolyte open and prevent the flow of shunt currents. The system and apparatus operate to separate commingled liquid dielectric and electrolyte flowing from the fuel cell sections; removes heat carried from the cell sections by the liquid dielectric; recommingles the liquid dielectric and electrolyte and reintroduces into the cell sections. The system and apparatus operate to intermittently transfer portions of partially spent byproduct ladened electrolyte circulated through the anode sections of the cells to a separator in which the byproduct is removed from the spent electrolyte.

DETAILED DESCRIPTION OF THE INVENTION In FIG.
1 of the drawings, I have diagrammatically illustrated my new system and apparatus related to the anode and ion exchange sections X and Y of one metal/air fuel cell C of a battery of fuel cells.
The fuel cell sections X and Y are diagrammatically shown as separate blocks.
In practice, the cell sections X and Y are, for example, adjacent related anode and ion exchange sections of a metal/air fuel cell structure such as is shown and described in my previously identified patent application Ser.
No.
458,835, entitled METAL/GAS FUEL CELL.
The purpose and function of my new system and apparatus is to handle and manage supplies of anolyte and ionolyte solutions A and I for the several sections X and Y of the battery of cells; to selectively put the battery of cells into and out of operation; to maintain the battery of cells at effective and efficient operating temperature; to maintain the electrolytes properly balanced for most effective and efficient operation of the battery of cells; to prevent the flow of shunt currents through the electrolytes and between related cell sections; to effectively recycle and conserve the noted electrolytes; and to salvage the solid byproducts of fuel cell reaction.
The apparatus that I provide first includes a supply tank S, shown at the right-hand side of FIG.
1 of the drawings.
The tank S holds a supply of base electrolyte solution E, such as an aqueous solution of sodium hydroxide and a supply of dielectric liquid K.
The liquid K is hydrophobic and non-soluble in or with the electrolyte solution E and has a specific gravity which is less than the specific gravity of the solution E.
The dielectric liquid K can be any one of several petroleum distillates.
In carrying out my invention, kerosene and anhydrous jet fuel have proven to be highly effective.
For the purpose of this disclosure, I will refer to the dielectric liquid as the dielectric K or liquid dielectric K.
The dielectric K in the tank S floats above or on top of the aqueous electrolyte solution E and is in effect separate therefrom



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