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Heavy crude conversion
| Details |
Inventors: Hamner, Glen P.;
Assignee: Exxon Research and Engineering Company (Linden, NJ)
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Schmitkons; G. E.
Attorney, Agent or Firm: Proctor; Llewellyn A.
This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree.F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree.F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e., one having properties inclusive of a large number of pores in the 100-275A pore size diameter range, is particularly suitable as a first stage catalyst and the other, which has properties inclusive of a large number of pores in the 100A-200A pore size diameter, is especially suitable as a second stage catalyst for use in processing the effluent of said first stage. |
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DETAILED DESCRIPTION Having described the invention, what is claimed is: 1. A process for the demetallization and conversion of the 1050. degree. F. + materials of a heavy metals containing hydrocarbon feed to 1050. degree. F. - material comprising contacting said feed in the presence of added hydrogen, with a catalyst characterized as comprising a composite of from about 5 to about 30 percent of a Group VIB metal, from about 1 to about 12 percent of a Group VIII metal, or admixture of said Group VIB and Group VIII metals, and a porous inorganic oxide support, said catalyst including a combination of properties comprising, when the catalyst is of size ranging up to 1/50 inch average particle size diameter, at least about 20 percent of its total pore volume of absolute diameter within the range of about 100A to about 200A; when the catalyst is of size ranging from about 1/50 inch up to 1/25 inch average particle size diameter, at least about 15 percent of its total pore volume of absolute diameter within the range of about 150A to about 250A; when the catalyst is of size ranging from about 1/25 inch to about 1/8 inch average particle size diameter, at least about 15 percent of its total pore volume of absolute diameter within the range of about 175A to about 275A; a surface area ranging at least about 200 m. sup. 2 /g to about 600 m. sup. 2 /g and a pore volume ranging from about 0. 8 cc/g to about 3. 0 cc/g, at severity sufficient to convert at least about 30 percent of the 1050. degree. F. + material to 1050. degree. F. - material, while removing at least about 80 percent of the heavy metals from the feed. 2. The process of claim 1 wherein from about 40 percent to about 60 percent of the 1050. degree. F. + material is converted to 1050. degree. F. -, and from about 85 percent to about 90 percent of the metals are removed from the bed. 3. The process of claim 1 wherein the feed is characterized as follows:
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Gravity, . degree. API -5 to 20
Heavy Metals, ppm 5-1000
1050
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