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 Hydrocarbon conversion process employing essentially alumina-free zeolites

Details
Inventors: Miller, Stephen J.;
Assignee: Chevron Research Company (San Francisco, CA)
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Chaudhuri; O.
Attorney, Agent or Firm: Newell; D. A., La Paglia; S. R., Roth; S. H.

A process for converting a hydrocarbonaceous feedstock in which a catalytically hydroprocessed or a catalytically reformed feedstock is contacted under cracking conditions with an essentially alumina-free intermediate pore size zeolitic catalyst and immediately thereafter with a second essentially alumina-free intermediate pore size zeolitic catalyst under cracking conditions less severe than the first contacting conditions. The less severe conditions in the second contacting stage are preferably obtained by employing a lower temperature, although use of a less active catalyst to attain this end is a possibility. A crystalline chromia silicate having a mole ratio of oxides SiO.sub.2 :Cr.sub.2 O.sub.3 of greater than about 20 to 1 and an intermediate pore size crystalline silicate of the ZSM-5 type having a mole ratio of oxides SiO.sub.2 :Al.sub.2 O.sub.3 of greater than about 200 are the preferred catalysts.

DETAILED DESCRIPTION What is claimed is: 1.
A process for converting a hydrocarbonaceous feedstock by subjecting the feedstock to catalytic reactions in three zones, the process comprising the steps of catalytically hydroprocessing the feedstock in a first reaction zone, contacting the product of the first zone in a second reaction zone under cracking conditions including a temperature of from about 650.
degree.
-1100.
degree.
F.
, a pressure of from about 0-2000 psig and an LHSV of from about 0.
1-10 with a first catalyst comprising an essentially alumina-free intermediate pore size zeolite and, immediately thereafter, contacting the product of the second reaction zone in a third reaction zone with a second catalyst comprising an essentially alumina-free intermediate pore size zeolite under cracking conditions less severe than the cracking conditions in the second reaction zone including a temperature of from about 400.
degree.
-700.
degree.
F.
, a pressure of from about 0-2000 psig and an LHSV of from about 0.
1-10 wherein the less severe cracking conditions are obtained by maintaining a lower temperature in the third reaction zone than in the second reaction zone so as to favor polymerization in the third zone of olefins formed in the second zone whereby selectivity to C.
sub.
5.
sup.
+ is increased.
2.
The process of claim 1 wherein the second and third reaction zones are contained within different reactors.
3.
The process of claim 1, wherein the first reaction zone is contained in a first reactor and the second and third reaction zones are contained in a second reactor.
4.
The process of claim 1 wherein the first and second catalysts comprise a ZSM-5 type crystalline silicate having a mole ratio of oxides SiO.
sub.
2 :Al.
sub.
2 O.
sub.
3 of greater than about 200.
5.
The process of claim 1 wherein the first and second catalysts comprise a ZSM-5 type crystalline silicate having a mole ratio of oxides SiO.
sub.
2 :Al.
sub.
2 O.
sub.
3 greater than about 500.
6.
The process of claim 1 wherein the first and second catalysts comprise a ZSM-5 type crystalline silicate having a mole ratio of oxides SiO



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