Molten carbonate fuel cell matrix tape and assembly method

DETAILED DESCRIPTION We claim: 1.
In the process of assembling a molten carbonate fuel cell including forming a fuel cell stack by stacking a plurality of electrodes separated by layers of matrix material, wherein the improvement comprises: inserting as the matrix material a matrix comprising particles inert to molten carbonate electrolyte having a particle size less than about one micron, ceramic particles having a particle size greater than about 25 microns, and an organic polymer binder material, the binder material being present in an amount of at least about 35% by volume, the matrix material being flexible, pliable, and compliant at room temperature, into the fuel cell stack, and utilizing as the fuel cell anode, an anode with sufficient porosity to contain sufficient electrolyte for continuous operation of the molten carbonate fuel cell for at least 40,000 hours.
2.
The process of claim 1 including heating the fuel cell stack containing the matrix and anode to a temperature for a time sufficient to remove the polymer binder and cause at least a portion of the electrolyte material in the anode to wick into and substantially completely fill the matrix.
3.
The process of claim 2 wherein the stack is heated from room temperature up to 205.
degree.
C.
at a rate of 40.
degree.
C.
per hour, held at 205.
degree.
C.
for 6 hours, then heated to 315.
degree.
C.
at a rate of 40.
degree.
C.
per hour and held at 315.
degree.
C.
for 6 hours, and then heated to 470.
degree.
C.
at a rate of 40.
degree.
C.
per hour and held at 470.
degree.
C.
for 2 hours, before being raised above the electrolyte melt temperature to a stack operating temperature of approximately 650.
degree.
C.
4.
The process of claim 1 wherein the inert particles are present in about 40% to about 45% by volume and the ceramic particles are present in an amount of at least about 15% by volume.
5.
The process of claim 1 wherein the polymer is polyvinyl butyral.
6.
The process of claim 1 wherein the inert material is lithium aluminate.
7.
The process of claim 1 wherein the ceramic particles are alumina