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 Multilayer protective coating and method

Details
Inventors: Keem, John E.; Flasck, James D.;
Assignee: Ovonic Synthetic Materials Company, Inc. (Troy, MI)
Primary Examiner: Swisher; Nancy
Assistant Examiner:
Attorney, Agent or Firm: Ryndak; James D., Norris; Lawrence G., Goldman; Richard M.

Multilayer protective coatings that are applied over a substrate are disclosed that comprise a plurality of superimposed multilayer units. Each multilayer unit contains two or more superimposed thin layers in which at least two layers are compositionally different. The properties of the resulting coating are a combination of the properties of the individual layers. One layer of a multilayer unit may provide hardness or wear resistance and another layer may provide lubricity, for example. The thickness of the individual layers can be related to the microscopic surface relief of the substrate to which the protective coating is applied.

DETAILED DESCRIPTION Referring to the figures generally and in particular to FIG.
1, there is illustrated greatly enlarged in sectional view a protective coating 10 in accordance with the invention that has been applied to a substrate 12.
As previously described, for wear applications, it is desirable that the substrate have microscopic surface relief or microscopic deviations from a planar surface.
This allows a plurality of the layers of protective coating 10 to be exposed during use, allowing the exposed surface to exhibit the properties of the materials present in the individual layers.
Substrate 12 is illustrated in perspective view in FIG.
2 prior to application of protective coating 10.
The surface 14 of substrate 12 to which protective coating 10 is applied is macroscopically planar but microscopically nonplanar having microscopic surface relief.
In this case, the surface relief consists of a plurality of peaks 16.
Peaks 16 are microscopic surface imperfections or defects which may or may not be essentially randomly oriented on surface 14.
Peaks 16 are illustrative of one type of microscopic surface relief imperfection which may be encountered.
Another type of microscopic surface imperfection consists of "ridges", shown and hereinafter described with respect to FIGS.
5-7.
Other microscopic surface imperfections may consist of, for example, combinations of peaks and ridges, or any type of variation from a planar surface.
Virtually every surface that will be encountered will have such microscopic deviations from a planar surface.
Protective coating 10 may be a wear resistant coating which is made up of a plurality of repeating overlaying multilayer units 18.
Each multilayer unit is made up of two compositionally different layers indicated in FIG.
1 by reference letters "a" and "b".
One or both layers of multilayer unit 18 may be chosen for hardness or wear resistance, or one layer may be chosen for hardness or wear resistance (aluminum oxide, for example) and the other layer chosen for lubricity (molybdenum diboride, for example)



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