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Details
Inventors: Ito, Shuji; Murata, Toshihide; Bito, Yasuhiko; Toyoguchi, Yoshinori;
Assignee: Matsushita Electric Industrial Co., Ltd. (Osaka-fu, JP)
Primary Examiner: Nuzzolillo; Maria
Assistant Examiner: Martin; Angela J.
Attorney, Agent or Firm: Akin, Gump, Strauss, Hauer & Feld, L.L.P.

The present invention provides a non-aqueous electrolyte secondary battery having an anode active material with a high capacity and excellent cycle characteristics. The active material comprises a salt of a metal or a semi-metal and a compound selected from the group consisting of oxo-acids, thiocyanic acid, cyanogen, and cyanic acid, wherein each said oxo-acid comprises an element selected from the group consisting of nitrogen, sulfur, carbon, boron, phosphorus, selenium, tellurium, tungsten, molybdenum, titanium, chromium, zirconium, niobium, tantalum, manganese, and vanadium, salts of said oxo-acids of phosphorus and boron being restricted to hydrogenphosphates and hydrogenborates.

DETAILED DESCRIPTION OF THE INVENTION As discussed above, the anode of the present invention comprises a metal salt or a semi-metal salt of a specific acid or cyanogen.
In the following description, salts of a divalent metal M.
sup.
II are given as examples.
Salts of nitrogen oxo-acids include nitrates M.
sup.
II (NO.
sub.
3).
sub.
2 and nitrites M.
sup.
II (NO.
sub.
2).
sub.
2.
Salts of sulfur oxo-acids include sulfates M.
sup.
II SO.
sub.
4, sulfites M.
sup.
II SO.
sub.
3, disulfates M.
sup.
II S.
sub.
2 O.
sub.
7, peroxomonosulfates M.
sup.
II SO.
sub.
5, peroxodisulfates M.
sup.
II S.
sub.
2 O.
sub.
8, thiosulfates M.
sup.
II S.
sub.
2 O.
sub.
3, disulfites M.
sup.
II S.
sub.
2 O.
sub.
5, thiosulfites M.
sup.
II S.
sub.
2 O.
sub.
2, hydrogensulfates such as M.
sup.
II (HSO.
sub.
4).
sub.
2, thionates such as dithionates M.
sup.
II S.
sub.
2 O.
sub.
6 and dithionites M.
sup.
II S.
sub.
2 O.
sub.
4, sulfoxylates such as M.
sup.
II SO.
sub.
2, and hydrogen-containing acid salts.
Preferable salts of phosphorus oxo-acids include hydrogenphosphates such as M.
sup.
II HPO.
sub.
4 and M.
sup.
II (H.
sub.
2 PO.
sub.
4).
sub.
2, phosphinates M.
sup.
II (PH.
sub.
2 O.
sub.
2).
sub.
2, and phosphonates M.
sup.
II PHO.
sub.
3.
Salts of carbon oxo-acids include carbonates M.
sup.
II CO.
sub.
3 and hydrogencarbonates M.
sup.
II (HCO.
sub.
3).
sub.
2.
Preferable salts of boron oxo-acids include hydrogenborates such as M.
sup.
II (H.
sub.
2 BO.
sub.
3).
sub.
2 and M.
sup.
II HBO.
sub.
3.
Salts of selenium oxo-acids include selenates M.
sup.
II SeO.
sub.
4, selenites M.
sup.
II SeO.
sub.
3, M.
sup.
II SeO.
sub.
5, hydrogenselenates M.
sup.
II (HSeO.
sub.
4).
sub.
2, and hydrogenselenites M.
sup.
II (HSeO.
sub.
3).
sub.
2.
Salts of tellurium oxo-acids include tellurates such as M.
sup.
II.
sub.
3 TeO.
sub.
6 and M.
sub.
II TeO.
sub.
4, and hydrogentellurates such as M.
sup.
II.
sub.
5 (H.
sub.
5 TeO.
sub.
6).
sub.
2, M.
sup.
II .
sub.
2 H.
sub.
2 TeO.
sub.
6, M.
sup.
II.
sub.
3 (H.
sub.
3 TeO.
sub.
6).
sub.
2, and M.
sup.
II H.
sub.
4 TeO.
sub.
6.
Available thiocyanates include M.
sup.
II (SCN).
sub.
2, while available cyanides and cyanates include M.
sup.
II (CN).
sub.
2 and M.
sup.
II (ONC).
sub.
2



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