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 Pre-water-based suspension alumina coated phosphor treatment process

Details
Inventors: Sigai, A. Gary;
Assignee: GTE Products Corporation (Danvers, MA)
Primary Examiner: Cooper; Jack
Assistant Examiner:
Attorney, Agent or Firm: Craig; Frances P., Ruoff; Carl F.

A method for eliminating carbonaceous contaminants and preventing the hydration/solubilization of the alumina protective coating of a phosphor is described. The method involves the heating a fluidized alumina coated phosphor in a fluidized bed at a temperature and for a period of time sufficient to preclude adversely affecting the protective oxide coating on the phosphor during subsequent water-based suspension processing without detrimentally altering the phosphor. After heating the fluidized phosphor is cooled and then added to a water-based suspension. The conditions for treating a manganese activated zinc silicate phosphor having a protective alumina coating are heating the fluidized phosphor at a temperature between about 700.degree. C. and about 850.degree. C. for a period of time from about 15 minutes to about 20 hours. A fluorescent lamp containing the phosphor prepared by the above described method is also described.

DETAILED DESCRIPTION In accordance with one aspect of the present invention, a new and improved method for the treatment of an alumina coated phosphor and having a particle size of about 10-12 microns comprises the following steps: Step 1--A phosphor having an alumina protective coating is fluidized in an isothermal fluidized bed to form a fluidized phosphor powder.
Step 2--The fluidized phosphor powder from Step 1 is heated at a temperature from about 700.
degree.
C.
to about 850.
degree.
C.
and for a period of time sufficient to preclude adversely affecting the alumina protective coating on the phosphor during subsequent water-based suspension processing and to preclude detrimentally altering the phosphor to form an annealed phosphor powder.
Step 3--The annealed phosphor powder from step 2 is cooled to form a cooled annealed phosphor powder.
Step 4--The cooled annealed phosphor powder from step 3 is added to a water-based suspension.



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