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Addition compounds suitable for use as dispersing agents and dispersion stabilizers, process for their production, their use and solids coated therewith
| Details |
Inventors: Haubennestel, Karlheinz; Pritschins, Wolfgang;
Assignee: BYK-Chemie GmbH (Wesel, DE)
Primary Examiner: Welsh; Maurice J.
Assistant Examiner:
Attorney, Agent or Firm: Foley & Lardner, Schwartz, Jeffery, Schwaab, Mack, Blumenthal & Evans
Addition compounds suitable for use as dispersing agents and dispersion stabilizers obtainable by reacting polyisocyanates having an average functionality from 2.5 to 10 with monohydroxy compounds, reacting the resulting reaction products with compounds of Formula II G--(E).sub.n II wherein E represents --OH, --NH.sub.2 and/or --NHR (wherein R represents an alkyl group having 1 to 4 carbon atoms), n represents 2 or 3, and G represents an aliphatic, cycloaliphatic and/or aromatic group, and further reacting the resulting reaction product with compounds of Formula III Z--Q III or IV Z--NH--Z IV wherein Q represents --OH, --NH.sub.2, --NHR (wherein R represents an alkyl group having 1 to 4 carbon atoms) or --SH, and Z represents a group which contains at least one acidic functional group, OH-group or Si(OR).sub.m (R').sub.3-m group (wherein R and R' represent alkyl groups having 1 to 10 carbon atoms and m=1-3). Optionally, OH-groups present in the reaction product may be further reacted with polycarboxylic acids or their anhydrides. The invention also relates to a process for producing these addition compounds, to their use, and to powdered or fibrous solids which are to be worked into liquid systems which are coated with these dispersing agents. |
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS The invention embraces, in the first instance, addition compounds and their salts suitable for use as dispersing agents and as dispersion stabilizers, obtainable by reacting polyisocyanates, hydroxy compounds and Zerewitinoff hydrogen as well as compounds containing at least one acidic functional group, hydroxy-group or alkoxysilyl-group, optionally in the presence of solvents and optionally in the presence of reaction catalysts, characterized in that they are obtainable by reacting polyisocyanates having an average functionality of 2. 5 to 10 (a) with monohydroxycompounds of the Formula I Y--OH I wherein Y has the following meanings: (i) aliphatic and/or cycloaliphatic hydrocarbon groups with 8 to 30 carbon atoms, the hydrogen atoms of which may be partially replaced by halogens or aryl residues, (ii) aliphatic, cycloaliphatic and/or aromatic groups containing at least one --O--, --NHCOO-- and/or --COO-- group, having an average molecular weight M. sub. n from 200 to 10,000, the hydrogen atoms of which may be partially replaced by halogens, in such an amount that 10 to 70%, preferably 15 to 45% and particularly preferably 20 to 40% of the NCO-- groups are reacted; (b) the resulting reaction product is reacted with compounds of the Formula II G--(E). sub. n II wherein E represents --OH, --NH. sub. 2, and/or --NHR (in which R represents an alkyl group having 1 to 4 carbon atoms) and n represents 2 or 3. and G represents an aliphatic, cycloaliphatic and/or aromatic group containing at least 2 carbon atoms having an average molecular weight M. sub. n of at most 3000, which may contain --O--, --COO--, --CONH--, --NHCOO--, --S--, --Si(CH. sub. 3). sub. 2 O-- and/or --SO. sub. 2 -- groups, in such an amount that a further 1 to 50%, preferably 5 to 45% and particularly preferably 15 to 40% of the NCO-- groups of the originally utilized polyisocyanate are reacted, whereby in the reactions (a) and (b) all total at least 20% and at most 85%, preferably 30 to 65% and particularly preferably 40 to 60% of the NCO-- groups of the originally utilized polyisocyanate are reacted, (c) the resulting reaction product is reacted with at least one of the compounds of the Formula III Z--Q III or IV Z--NH--Z IV wherein Q represents --OH, --NH
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