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Details
Inventors: Dhanani, Shafiq; MacDonald, Ronald; Clunie, James S.; Brooks, Maxim C.;
Assignee: The Procter & Gamble Company (Cincinnati, OH)
Primary Examiner: Smith; John D.
Assistant Examiner: Bell; Janyce A.
Attorney, Agent or Firm:

Foam-controlled detergent compositions comprising alkoxylated nonionic surfactant, polydimethylsiloxane foam-controller dispersed therein, and siloxane-oxyalkylene copolymer as dispersing agent therefor, the weight ratio of polydimethylsiloxane to dispersing agent lying in the range from 2:1 to 20:1. The compositions preferably also contain particulate silica in a weight ratio of polydimethylsiloxane to silica of from 20:1 to 200:1.

DETAILED DESCRIPTION What we claim is: 1.
A foam-controlled detergent composition comprising from 1.
5% to 100% of a mixture of: (a) alkoxylated nonionic surfactant, (b) polydimethylsiloxane foam controller dispersed in at least part of the alkoxylated nonionic surfactant, and (c) siloxane-oxyalkylene copolymer as dispersing agent for the polydimethylsiloxane foam controller, wherein the weight ratio of alkoxylated nonionic surfactant to polydimethylsiloxane foam controller is in the range from 10:1 to 100:1 and the weight ratio of polydimethylsiloxane foam controller to siloxane-oxyalkylene copolymer is in the range from 2:1 to 20:1.
2.
A composition according to claim 1 wherein the polydimethylsiloxane foam controller is dispersed in the nonionic surfactant together with particulate silica in a weight ratio of polydimethylsiloxane to silica in the range from 20:1 to 200:1.
3.
A composition according to claim 2 wherein the weight ratio of alkoxylated nonionic surfactant to polydimethylsiloxane foam controller is in the range from 25:1 to 65:1 and the weight ratio of polydimethylsiloxane foam controller to siloxane-oxyalkylene copolymer is in the range from 5:1 to 15:1.
4.
A composition according to claim 1 wherein the siloxaneoxyalkylene copolymer has the general formula I: R.
sub.
a SiY.
sub.
4-a I wherein a is 0 or an integer from 1 to 3, R is an alkyl group containing from 1 to 30 carbon atoms, or a group of formula II: R'(OR').
sub.
b OR" II wherein R' is an alkylene group containing from 1 to 6 carbon atoms, b has a value of from 1 to 100; and R" is a capping group which is selected from hydrogen, alkyl, acyl, aryl, alkaryl, aralkyl or alkenyl groups containing up to 20 carbon atoms, sulfate, sulfonate, phosphate, carboxylate, phosphate, borate or isocyanate groups, or mixtures thereof: Y is a group having the formula III: ##STR2## wherein R is as defined above and c has a value from 1 to 200; and wherein at least one R group in the compound has the formula II.
5.
A composition according to claim 4 wherein the siloxane-oxyalkylene copolymer is selected from copolymers having the general formula IV to VII: R'''



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