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Home Image Analysis Lithium-ion-containing-organic-electrolyte

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 Lithium ion-containing organic electrolyte

Details
Inventors: Louzos, Demetrios V.; Brodd, Ralph J.;
Assignee: Union Carbide Corporation (New York, NY)
Primary Examiner: Tufariello; T. M.
Assistant Examiner:
Attorney, Agent or Firm:

A lithium ion-containing solvent-electrolyte suitable for the electrodeposition of lithium in electrochemical cells, said electrolyte comprising lithium fluoroborate dissolved in a mixture of methylene chloride and sulfolane and/or the alkyl-substituted derivatives thereof.

DETAILED DESCRIPTION What is claimed is: 1.
A solvent-electrolyte for use in a lithium electrodeposition process comprising an ionizable solute of lithium fluoroborate dissolved in a solvent mixture of methylene chloride and at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivatives thereof.
2.
The solvent-electrolyte of claim 1 wherein said lithium fluoroborate is present in a concentration of about 3 percent by weight based on the weight of the solvent mixture up to saturation of the lithium fluoroborate in the solvent mixture.
3.
The solvent-electrolyte of claim 1 wherein the at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivatives thereof is between about 20 and about 80 volume percent of the electrolyte solvent mixture.
4.
The solvent-electrolyte of claim 2 wherein the at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivative thereof is betwen about 20 and about 80 volume percent of electrolyte solvent mixture.
5.
The solvent-electrolyte of claim 4 wherein the at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivatives thereof is between about 50 and about 60 volume percent of the electrolyte solvent mixture.
6.
A process for electrodeposition of lithium from a nonaqueous electrolyte wherein said electrodeposition is carried out with an electrolyte of lithium fluoroborate dissolved in a solvent mixture of methylene chloride and at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivatives thereof.
7.
The process of claim 6 wherein said lithium fluoroborate is present in a concentration of about 3 percent by weight based on the weight of the solvent mixture up to saturation of the lithium fluoroborate in the solvent mixture.
8.
The process of claim 6 wherein the at least one additional solvent selected from the group consisting of sulfolane and the alkyl-substituted derivatives thereof is between about 20 and about 80 volume percent of the electrolyte solvent mixture



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