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Home LCD Process-for-separation-of-zirconium-from-hafnium

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 Process for separation of zirconium from hafnium

Details
Inventors: Peterson, Steven H.; Jackovitz, John F.;
Assignee: Westinghouse Electric Corp. (Pittsburgh, PA)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

A process for the separation of zirconium values from hafnium values wherein a solution of a zirconium chelate complex and a hafnium chelate complex, each having a common ligand, is irradiated with light, of a wavelength between 300 nm and 700 nm, in the presence of a scavenger, such that one of the metal chelate complexes is excited and reacts with the scavenger to form a reaction product that is separated from the solution while the other of the metal chelate complex remains stable and is retained in the solution.

DETAILED DESCRIPTION The separation of zirconium from hafnium is effected by forming a solution of complexes of the metals, containing a common organic ligand, where one of the complexes is excitable by light while the other complex remains stable, using light having a wavelength between 300 nm to 700 nm, and irradiating the solution with light within that wavelength, in the presence of a scavenger, to excite the one complex and cause reaction thereof with the scavenger, and separation thereof from the solution, while the other complex remains stable in said solution.



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