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Home Liquid Purification Catalytic-conversion-of-olefins-to-higher-hydrocarbons

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 Catalytic conversion of olefins to higher hydrocarbons

Details
Inventors: Owen, Hartley; Marsh, Susan K.; Wright, Bernard S.;
Assignee: Mobil Oil Corporation (New York, NY)
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Pal; A.
Attorney, Agent or Firm: McKillop; A. J., Gilman; M. G., Wise; L. G.

An improved continuous process for converting lower olefinic hydrocarbon feedstock to C.sub.5.sup.+ liquid hydrocarbons by contacting vapor phase olefinic feedstream with acid zeolite catalyst in the presence of recycled diluent stream rich in C.sub.3 -C.sub.4 hydrocarbons in an enclosed reactor at elevated temperature and pressure. The improved technique comprises a system for cooling reactor effluent to recover a heavier hydrocarbon stream containing a mixture of C.sub.3 -C.sub.4 hydrocarbons and C.sub.5.sup.+ hydrocarbons and debutanizing the heavier hydrocarbons below reactor pressure to obtain a C.sub.5.sup.+ product stream and a condensed C.sub.3 -C.sub.4 hydrocarbon stream. Operating efficiencies are realized in the heat exchange system by reboiling the debutanized C.sub.5.sup.+ hydrocarbon product stream with hot reactor effluent, and by recycling and combining at least a portion of the condensed C.sub.3 -C.sub.4 hydrocarbon stream to dilute liquid olefin hydrocarbon feedstock. By increasing pressure on the liquid olefinic hydrocarbon feedstock and liquid recycle stream to at least the elevated reactor pressure in the liquid state prior to vaporization, energy is conserved.

DETAILED DESCRIPTION What is claimed is: 1.
A continuous process for converting lower olefins to higher hydrocarbons with optional operation to maximize either distillate or gasoline product comprising: (a) combining a pressurized liquid olefinic feedstock containing a substantial fraction of lower olefins with a pressurized liquid low alkane stream comprising a major fraction of C.
sub.
3 -C.
sub.
4 alkanes; (b) pre-heating the combined olefinic stream and lower alkane stream to a temperature of at least about 230.
degree.
C.
; (c) contacting the pre-heated combined olefinic stream with an acid ZSM-5 type catalyst in a pressure reactor zone to convert a major portion of the lower olefin fraction to C.
sub.
5.
sup.
+ hydrocarbons in the gasoline boiling and distillate range; (d) cooling the reactor effluent from step (c); (e) debutanizing the cooled reactor effluent directly at less than reactor pressure to recover condensed lower alkane stream and a liquid C.
sub.
5.
sup.
+ hydrocarbon stream, including heat exchanging the reactor effluent indirectly with the liquid C.
sub.
5.
sup.
+ hydrocarbon stream in a debutanizer reboiler section; (f) recycling and pumping to reactor pressure at least a portion of the condensed lower alkane stream to step (a); and (g) fractionating the C.
sub.
5.
sup.
+ hydrocarbon stream to obtain a distillate product fraction and a gasoline-boiling range fraction.
2.
The process of claim 1 wherein the olefinic feedstock consists essentially of C.
sub.
2 -C.
sub.
5 aliphatic hydrocarbons containing a major fraction of monoalkenes in the essential absence of dienes or other deleterious materials.
3.
The process of claim 2 wherein the olefinic feedstock contains about 50 to 75 mole % C.
sub.
3 -C.
sub.
5 alkenes; wherein said pre-heated combined stream is contacted with the catalyst at a weight hourly space velocity of about 0.
5 to 2; wherein said recycled lower alkane contains at least 80 mole % C.
sub.
3 -C.
sub.
4 alkanes and is combined with olefinic feedstream at a mole ratio of about 0.
5:1 to 2:1, based on olefin in fresh feed; and wherein said catalyst comprises HZSM-5



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