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 Destruction of DNPI in an all nitric acid nitration process
OF THE INVENTION For the purpose of this specification and the appended claims, the "boiling point ...


 Process for the preparation of n-alkylphthalimide and copolymer derived therefrom
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 Method for making N-substituted nitrophthalimides
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 Process for the preparation of 4-bromophthalic anhydride
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 Preparation of halogen substituted phthalic anhydride
OF THE INVENTION This invention is concerned with the aromatization of a cyclic compound to form a ...


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 Preparation of halogenated phthalic anhydrides
OF THE INVENTION The present invention provides a process for aromatizing 4,5-...


 Nitration of phthalic acid and phthalic anhydride using nitric acid
OF THE INVENTION For the purpose of this specification and the appended claims, the "boiling point ...


 Phase transfer catalyzed preparation of aromatic polyether polymers
What is claimed is: 1. A method for preparing an aromatic polyether polymer which comprises ...


 Catalyst for producing phthalic anhydride and process by using the same
The present invention provides a catalyst further improved on the catalyst performance compared ...


 Crosslinkable low viscosity star polymer blends

Details
Inventors: Handlin, Jr., Dale L.; Erickson, James R.; Stewart, David R.;
Assignee: Shell Oil Company (Houston, TX)
Primary Examiner: Seidleck; James J.
Assistant Examiner: Clark; W. Robinson H.
Attorney, Agent or Firm: Haas; Donald F.

A crosslinkable low viscosity short arm star polymer blend made by anionically polymerizing a conjugated diene and, optionally, a vinyl aromatic hydrocarbon to form living polymer arms and coupling said arms with a coupling agent for star polymers and blending said star polymer with a compatible organic liquid such that the amount of organic liquid in the blend ranges from 5 to 50 percent by weight. A preferred embodiment is an epoxidized version which is selectively epoxidized at the exterior sections of the polymer to enhance the crosslinkability of the polymer.

DETAILED DESCRIPTION OF THE INVENTION Polymers containing ethylenic unsaturation can be prepared by copolymerizing one or more polyolefins, particularly a diolefin, by themselves or with one or more alkenyl aromatic hydrocarbon monomers.
The copolymers may, of course, be random, tapered, block or a combination of these, as well as linear, star or radial.
The polymers containing ethylenic unsaturation or both aromatic and ethylenic unsaturation may be prepared using anionic initiators or polymerization catalysts.
Such polymers may be prepared using bulk, solution or emulsion techniques.
In any case, the polymer containing at least ethylenic unsaturation will, generally, be recovered as a solid such as a crumb, a powder, a pellet or the like, but it also may be recovered as a liquid such as in the present invention.
Polymers containing ethylenic unsaturation and polymers containing both aromatic and ethylenic unsaturation are available commercially from several suppliers.
In general, when solution anionic techniques are used, copolymers of conjugated diolefins and alkenyl aromatic hydrocarbons are prepared by contacting the monomer or monomers to be polymerized simultaneously or sequentially with an anionic polymerization initiator such as group IA metals, their alkyls, amides, silanolates, napthalides, biphenyls or anthracenyl derivatives.
It is preferred to use an organo alkali metal (such as sodium, lithium, or potassium) compound in a suitable solvent at a temperature within the range from about -150.
degree.
C.
to about 300.
degree.
C.
, preferably at a temperature within the range from about 0.
degree.
C.
to about 100.
degree.
C.
Particularly effective anionic polymerization initiators are organo lithium compounds having the general formula: RLi.
sub.
n wherein R is an aliphatic, cycloaliphatic, aromatic or alkyl-substituted aromatic hydrocarbon radical having from 1 to about 20 carbon atoms and n is an integer of 1 to 4.
Conjugated diolefins which may be polymerized anionically include those conjugated diolefins containing from about 4 to about 24 carbon atoms such as 1,3-butadiene, isoprene, piperylene, methylpentadiene, phenylbutadiene, 3,4-dimethyl-1,3-hexadiene, 4,5-diethyl-1,3-octadiene and the like



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