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 Elastomeric composition

Details
Inventors: Wyman, Ransome J.;
Assignee:
Primary Examiner: Jacobs; Lewis T.
Assistant Examiner:
Attorney, Agent or Firm: Nilsson, Robbins, Dalgarn, Berliner, Carson & Wurst

A method and composition are provided for preparing elastomeric polymers containing a particulate rubber filler which are useful to provide relatively thick membranes for flooring, decking, roofing or other purposes and which permit the molding of a wide variety of rubber-like goods. The composition comprises a polyol, an organic polyisocyanate, an alkaline carbon dioxide absorbent and a water carrier in amounts sufficient to form a non-foaming pourable, trowelable or sprayable composition, includes rubber particles to provide increased resiliency, economy and density, and cures internally to provide a polyurethane elastomer coating. A prepolymer may be prepared as a separate component having an extended shelf life and adapted for ultimate combination with an aqueous rubber slurry in order to facilitate simple on site mixing of the composition.

DETAILED DESCRIPTION While the invention will be exemplified by reference to a specific polyurethane elastomeric polymer, the invention in general and certain aspects in particular are broad in scope, for example, the concepts of curing a particulate rubber containing polyurethane elastomer with an excess of water and including an alkaline component to absorb the carbon dioxide produced thereby, and providing a method whereby a prepolymer component and a water-particulate rubber slurry may be easily mixed to form a superior coating membrane.
Consequently, specific details disclosed herein are merely representative and are deemed to afford the best embodiments at this time known to provide a basis for the claims which define the scope of the present invention.
The polyol can be chosen from a variety of OH terminated polyethers.
Preferred are the polyoxyalkylene polyols having two-four hydroxyl groups and where the alkylene group has 2-6 carbon atoms.
A large variety are available, obtained by polymerization of an aklylene oxide, such as ethylene oxide, probylene oxide or butylene oxide with a glycol.
Polyethers having higher functionality may be obtained by reaction with a diol, triol or higher polyol, such as glycerine, trimethylol propane, and pentaerythritol.
Polyols of the above types are available commercially, for example: Voranols (Trademark), Dow Chemical Company: Poly-G (Trademark) from Olin Chemicals Division; and Pluracols (Trademark) from BASF Wyandotte Corporation.
In particular, a predominantly polypropylene-oxide triol having a molecular weight of at least 1,000 is most suitable.
Polyols may be used up to a molecular weight which produces a viscosity in excess of that required for the desired application.
Polyols having a molecular weight of less than about 500 begin to lose some elastomeric properties and those having a molecular weight of less than about 200 become rigid and produce large amounts of carbon dioxide.
Polyols having a high ethylene oxide content on the backbone show increased reactivity, i



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