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 Hardenable compositions

Details
Inventors: Crisp, Stephen; Wilson, Alan D.;
Assignee: National Research Development Corporation (GB2)
Primary Examiner: Bleutge; John C.
Assistant Examiner: Lilling; Hebert
Attorney, Agent or Firm: Jacobs & Jacobs

Compositions which are hardenable in the presence of water to form a poly(carboxylate) cement contain a metal salt which accelerates the setting of the composition.

DETAILED DESCRIPTION We claim: 1.
A hardenable composition which comprises (i) a poly(carboxylic acid) selected from the group consisting of homopolymers and copolymers of unsaturated aliphatic carboxylic acids or precursor thereof that is converted to said poly(carboxylic acid) on hydrolysis thereof; (ii) a particulate ion-leachable silicate or aluminosilicate glass reactable with (i) in the presence of water to set to a hardened composition; and (iii) an inorganic metal salt which accelerates the setting of the composition selected from the group consisting of a silver (I) salt, a barium salt and a multivalent metal salt, the cation of which has a standard electrode potential E.
sub.
ox.
sup.
o less than 2.
6 volts.
2.
A hardenable composition according to claim 1 wherein (iii) comprises a silver (I) salt or a barium salt.
3.
A hardenable composition according to claim 2 wherein (iii) comprises silver nitrate, barium chloride or barium fluoride.
4.
A hardenable composition according to claim 1 wherein (i) comprises an acrylic acid homopolymer or copolymer of acrylic acid with one or more of aconitic, fumaric, itaconic, maleic, mesaconic, methacrylic, muconic, or tiglic acid.
5.
A hardenable composition according to claim 1 wherein (iii) comprises a multivalent metal salt the cation of which has a standard electrode potential E.
sub.
ox.
sup.
o less than 2.
6 volts.
6.
A hardenable composition according to claim 5 wherein (iii) comprises a salt of aluminium, cadmium, magnesium, mercury (II), silver (II), or zirconium.
7.
A hardenable composition according to claim 6 wherein (iii) comprises a salt of aluminium, magnesium, silver (II) or zirconium.
8.
A hardenable composition according to claim 1 wherein (iii) comprises a fluoride.
9.
A hardenable composition according to claim 8 wherein (iii) comprises aluminium fluoride, magnesium fluoride, stannous fluoride, silver difluoride or zinc fluoride.
10.
A hardenable composition according to claim 1 wherein (iii) is soluble in an aqueous solution of (i)



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