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Method for preparing poly-N-alkenylamines
| Details |
Inventors: Sirotkina, Ekaterina Egorovna; Filimonov, Viktor Dmitrievich; Sizova, Ljubov Sergeevna; Tsekhanovskaya, Nina Alexandrovna;
Assignee:
Primary Examiner: Phynes; Lucille M.
Assistant Examiner:
Attorney, Agent or Firm: Holman & Stern
A method for preparing poly-N-alkenylamines having the following formula (I) ##EQU1## WHERE A is a tertiary aromatic or heterocyclic amine, connected to a carbon atom through nitrogen, R and R' are similar or different hydrogen or lower alkyl, and n is the degree of polymerization, consisting in that the secondary aromatic or heterocyclic amines or their derivatives, for example, diphenylamine, carbazole, phenthiazine, phenoxazine, 3-chloro- and 3,6-dichlorocarbazole are treated with aldehydes having the formula (II) RR'CH-CH=O, where R and R.sup.1 are the substances specified above, or their polymers capable of depolymerizing in an acid medium, in the presence of acid catalysts, in organic solvents. The said polymers are prepared by a single-step process without the separation of any intermediate products; the products prepared possess photosensitive properties and can be used, for example, in electrophotography and related processes. |
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DETAILED DESCRIPTION We claim: 1.
A method for preparing thermoplastic poly-N-alkenylamines having the general formula ##EQU2## where A is a tertiary heterocyclic amine, connected to the carbon atom through the nitrogen, R and R' are selected from the group consisting of hydrogen and lower alkyl, and n is the degree of polymerization, comprising reacting a secondary heterocyclic amine or derivatives thereof, with an aldehyde having the general formula RR'CH-CH=O, where R and R' are the substituents as specified above, or polymers thereof capable of depolymerizing in an acid medium, in the presence of an acid catalyst, and in an organic solvent.
2.
A method according to claim 1, wherein said secondary amine is selected from the group consisting carbazole, phenthiazine, phenoxazine, 3-chloro- and 3,6-dichlorocarbazoles, or derivatives, thereof.
3.
A method according to claim 1, wherein said aldehyde is selected from the group consisting of acetaldehyde, propionic aldehyde, butyric aldehyde and isobutyric aldehyde.
4.
A method according to claim 1, wherein paraldehyde is used as the aldehyde.
5.
A method according to claim 1, wherein strong proton-donating acids and Lewis acids selected from the group consisting of sulphuric, perchloric, hydrochloric acids, mixtures thereof, and the etherate of boron trifluoride are used as the catalysts.
6.
A method according to claim 1, wherein the organic solvent is selected from the group consisting of aliphatic ketones, aromatic and chlorinated paraffin and aromatic hydrocarbons, nitroparaffins and dioxane.
7.
A method according to claim 1, further comprising reacting said secondary amine and said aldehyde in the presence of an accelerator selected from the group consisting of carboxylic acids, anhydrides of carboxylic acids and aliphatic alcohols.
8.
A method according to claim 1, wherein said secondary amine is selected from the group consisting of carbazole, 3-chlorocarbazole, and 3,6-dichlorocarbazole.
9.
A method according to claim 8, wherein said aldehyde is monomeric
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Manufacturing Materials 
