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Home Manufacturing Materials Method-for-preventing-scale-formation-and-corrosion-in-circulating-water

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Details
Inventors: Yamaguchi, Shigeru; Fujisawa, Takashi;
Assignee: Nippon Shokubai Co., Ltd. (Osaka, JP); Kurita Water Industries, Ltd. (Tokyo, JP)
Primary Examiner: Henderson; Christopher
Assistant Examiner:
Attorney, Agent or Firm: Oblon, Spivak, McClelland, Maier & Neustadt, P.C.

An agent for water treatment comprises a water-soluble polymer obtained by polymerizing a monomer component containing a water-soluble monomer capable of dissolving in water of 50.degree. C. in the amount of 1 weight % or more, having an ethylenically unsaturated group, and exhibiting fluorescence. The water-soluble polymer has a ratio of fluorescence intensity FL.sub.1 /FL.sub.2 larger than 1, wherein FL.sub.1 is an intensity of fluorescence obtained in dissolving a water-soluble polymer in a concentration of 10 ppm in pure water, and FL.sub.2 is an intensity of fluorescence obtained in dissolving phenol in a concentration of 0.1 ppm in pure water.

DETAILED DESCRIPTION In view thereof, it is an object of the present invention to provide an agent for water treatment comprising a water-soluble polymer capable of being produced by polymerization in an aqueous system and of measuring the concentration of water-soluble polymer existing in water to be treated in a simplified, speedy and accurate manner.
An agent for water treatment according to the present invention comprises a water-soluble polymer obtained by polymerizing a monomer component containing a water-soluble monomer capable of dissolving in water of 50.
degree.
C.
in the amount of 1 weight % or more, having an ethylenically unsaturated group, and exhibiting fluorescence, the water-soluble polymer having a ratio of fluorescence intensity FL.
sub.
1 /FL.
sub.
2 larger than 1, wherein FL.
sub.
1 is an intensity of fluorescence obtained in dissolving a water-soluble polymer in the concentration of 10 ppm in pure water, and FL.
sub.
2 is an intensity of fluorescence obtained in dissolving phenol in the concentration of 0.
1 ppm in pure water.
The water-soluble monomer may preferably have an oxyalkylene chain represented by --?CHR.
sup.
1 (CH.
sub.
2).
sub.
m O!.
sub.
n -- to show a favorable water solubility, wherein R.
sup.
1 is a hydrogen or a methyl group, m is an integer from 1 to 3, and n is an integer from 1 to 100.
In particular, the water-soluble monomer may preferably be represented by the following formula I: ##STR1## wherein A.
sup.
1 and A.
sup.
2 are independently a hydrogen, a methyl group or --COOX, respectively; A.
sup.
3 is a hydrogen, a methyl group, --COOX or --CH.
sub.
2 COOX; and A.
sup.
1 and A.
sup.
2 are not --COOX at the same time; A.
sup.
1 and A.
sup.
2 are independently a hydrogen or a methyl group respectively when A.
sup.
3 is --COOX or --CH.
sub.
2 COOX; X is a hydrogen, an alkaline metal, an alkaline earth metal, an ammonium group or an organic amine group; R.
sup.
2 is one of --COO--, --CH.
sub.
2 COO--, --CONH--, --CH.
sub.
2 CONH--, --NH--, --(CH.
sub.
2).
sub.
k NH--, wherein k is an integer from 1 to 4, and --(CH



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