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 Method of depositing thin films of small dimensions utilizing silicon nitride lift-off mask

Details
Inventors: Havas, Janos; Paal, Gabor;
Assignee: International Business Machines Corporation (Armonk, NY)
Primary Examiner: Newsome; John H.
Assistant Examiner:
Attorney, Agent or Firm: Sughrue, Rothwell, Mion, Zinn and Macpeak

A method for depositing thin film patterns of very small and controllable dimensions in the fabrication of integrated circuits which avoids edge tearing of the films. A non-photosensitive organic polymeric first masking layer is deposited on the integrated circuit substrate. Upon this layer is deposited a layer of silicon nitride using plasma deposition techniques employing a gaseous source. The silicon nitride layer is covered by a second masking layer, preferably an organic polymeric resist material, through which apertures are formed in preselected patterns using standard lithographic masking and etching techniques. The silicon nitride layer is then reactive ion etched with CF.sub.4 through the apertures formed in the second masking layer. The first masking layer is then etched through the apertures in the second masking layer and silicon nitride layer using reactive ion etching techniques. The etching of the first masking layer continues until the first masking layer is undercut beyond the edges of the aperture in the silicon nitride layer so that the silicon nitride layer forms an overhang of the aperture in the first masking layer. The thin film to be deposited is then applied over the resulting structure including the surface of the silicon nitride layer and the substrate exposed through the apertures. Because of the overhang, a discontinuity is formed between the thin film deposited upon the exposed surface of the substrate and that formed upon the outer surface of the silicon nitride layer so that when the first masking layer is dissolved, the film deposited upon the substrate is left without any edge tearing between it and the removed portions of the film.

DETAILED DESCRIPTION Accordingly, it is a primary object of the invention to provide an improved tear-free thin film deposition process in which the dimensions of the film are very precisely controllable and in which the width of the film can be made exceedingly small with correspondingly small distances between adjacent areas of deposited film.
It is another object of the present invention to provide such a thin film deposition method in which the various masking layers can be deposited with a uniform thickness and in which the etch rates of the various layers can be precisely controlled.
It is still a further object of the present invention to provide such a thin film deposition method in which the dimensions of the deposited film are determined precisely by a photolithographic mask.
Yet another object of the present invention is to provide such a thin film deposition technique in which the photolithographic mask can be optically aligned without the use of specially provided alignment areas which reduce the amount of available wafer area.
These, as well as other objects of the invention, may be met by a method in which an integrated circuit substrate or wafer is first covered with a first masking layer, preferably of an organic polymeric material such as a photoresist material, which is rendered non-photosensitive.
This may be baked on to promote adherence.
Upon the first masking layer is then deposited a layer of silicon nitride material.
Apertures are formed in the layer of silicon nitride material using standard photolithographic and ion etching techniques.
For example, the layer of silicon nitride material may be covered with a second masking layer of photoresist material, the second masking layer of photoresist material exposed through a photolithographic mask and developed to remove the portions of the second layer of masking material which correspond to the desired aperture patterns in the layer of silicon nitride material.
The silicon nitride material may be then etched through the apertures in the second masking layers, for example, as by reactive ion etching using carbon tetrafluoride



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