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 Methods and apparatus for controlling toxic compounds using catalysis-assisted non-thermal plasma

Details
Inventors: Yamamoto, Toshiaki;
Assignee:
Primary Examiner: Gorgos; Kathryn L.
Assistant Examiner: Mayekar; Kishor
Attorney, Agent or Firm: Myers Bigel Sibley & Sajovec, P.A.

The present invention provides methods and apparatus for decomposing toxic compounds so that reaction by-products produced thereby are selectively reduced. A method generally comprises: introducing a carrier gas, having a toxic compound entrained therein, into a packed-bed of ferroelectric pellets; and polarizing the pellets to produce a plasma which decomposes the toxic compound. The pellets are coated with a catalyst selected to react with by-products of the decomposition of the toxic compound and thereby produce non-toxic compounds. An apparatus for decomposing toxic compounds and selectively reducing by-products, according to the present invention, comprises: a vessel having an internal passageway therethrough; a packed-bed of pellets coated with at least one catalyst; means for producing a plasma within the packed-bed of pellets; and carrier gas flow means in fluid communication with the internal passageway for causing a carrier gas entrained with toxic compounds to flow through the packed-bed of pellets. The present invention also discloses methods and apparatus wherein a pulsed corona reactor having a catalyst coating on a portion thereof is utilized to decompose toxic compounds.

DETAILED DESCRIPTION It is therefore an object of the present invention to provide methods and apparatus for controlling undesirable by-products produced by the decomposition of toxic compounds using single-staged, catalysis-assisted non-thermal plasma techniques.
It is yet another object of the present invention to provide methods and apparatus for decomposing toxic compounds using non-thermal plasma wherein by-products of the decomposition reaction are eliminated within a single-staged reactor.
These and other objects are provided, according to one aspect of the present invention, by a method for decomposing toxic compounds with catalysis-assisted, non-thermal plasma so that by-products produced thereby are reduced, comprising the steps of: introducing a carrier gas, having a toxic compound entrained therein, through a packed-bed of ferroelectric pellets coated or impregnated with a catalyst; and polarizing the pellets to produce a plasma to decompose the toxic compound.
By-products are produced by the decomposition process.
The pellets may be formed of a material selected from various high dielectric materials (relative dielectric constant greater than approximately 5) including, but not limited to, barium titanate, strontium titanate, niobium titanate, and various ceramics.
The pellets are typically between about 0.
5 millimeter and 5.
0 millimeters.
An active catalyst is selected to react with the decomposition products, and may be selected from a variety of elements and compounds including, but not limited to, oxidation catalysts using noble metals, metal oxides, and reducing catalysts.
Exemplary catalysts include, but are not limited to, cobalt, copper, chromium, nickel, vanadium, platinum/aluminum oxides (Pt/Al.
sub.
2 O.
sub.
3), palladium/aluminum oxides (Pd/Al.
sub.
2 O.
sub.
3), rhodium, rhodium/zinc oxides (RhZnO.
sub.
2), ferrous oxide, ferric oxide, and zeolite.
Additionally, the pellets may be coated or impregnated with a plurality of catalysts.
The carrier gas comprises a gas selected from, but not limited to, air, oxygen, nitrogen, argon, and may be entrained with toxic compounds including, but not limited to, VOCs; CFCs; PFCs; halons; sulfur and nitrogen compounds; and ammonia



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