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Process and apparatus for embossing with cylinders having protrusions inclined in two directions |
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Method for producing high pressure laminates |
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Method for producing pulp using pre-treatment with stabilizers and defibration |
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Polyamine-epihalohydrin resinous reaction products |
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Polyamine/epihalohydrin reaction products |
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Temporary wet strength resins and paper products containing same |
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Control scheme for rapid pulp delignification and bleaching |
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Paper sizing composition and method |
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N-cycloalkyl substituted-10,11-dihydro 5H-dibenzo[a,d] cyclohepten-5-imines
| Details |
Inventors: Ciganek, Engelbert;
Assignee: E. I. Du Pont de Nemours and Company (Wilmington, DE)
Primary Examiner: Schwartz; Gerald A.
Assistant Examiner:
Attorney, Agent or Firm: Mentis; A. P.
5H-dibenzo[a,d]cyclohepten-5-imines having a cyclic alkyl group, such as cyclopropyl or cyclobutyl, and their 10,11-dihydro derivatives, are useful as plasticizers for polymers and also for their effect on the central nervous systems of mammals. |
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DETAILED DESCRIPTION The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows: 1. A compound of the structure ##SPC10## wherein Z is -CH. sub. 2 CH. sub. 2 - or -CH=CH-; R and R' are H; X is hydrogen or halogen and m and n individually are 0 or 1. 2. A compound according to claim 1 wherein Z is -CH. sub. 2 -CH. sub. 2 -. 3. A compound according to claim 1 wherein Z is -CH=CH-. 4. A compound according to claim 2 wherein X is H. 5. The compound of claim 1 wherein X is H, Z = -CH. sub. 2 -CH. sub. 2 -, m=1, n=0, and R and R' are H; N-cyclopropylmethyl-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-imine. 6. The compound of claim 1 wherein Z = -CH. sub. 2 -CH. sub. 2 -, X is H, m and n=0 and R=R'=H; N-cyclopropyl-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-imine. 7. The compound of claim 1 wherein Z = -CH. sub. 2 -CH. sub. 2 -, m=1, n=0, X=Cl and R=R'=H; 3-chloro-N-cyclopropylmethyl-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-im ine.
Description:
BACKGROUND OF THE INVENTION Field of the Invention This invention relates to novel cycloalkyl imines of dibenzocycloheptenes useful as plasticizers for polymers and for their effect on the central nervous system of mammals. 2. Description of Prior Art Numerous tricyclic compounds have been made including dibenzocycloheptane derivatives. None of these have a cycloalkyl containing imino group attached to nuclear carbon of the seven membered ring. Some oximes have been reported in U. S. Pat. Nos. 3,441,608 and 3,526,631. Belgian patent No. 773,649 published Apr. 10, 1972 shows alkylamino dibenzocycloheptane imines which are different from the compounds of this invention. U. S. Pat. No. 3,780,106 issued on Dec. 18, 1973 appears to show straight chain alkyl imines of dibenzocycloheptane but does not disclose any biological or plasticizing properties. DESCRIPTION OF THE INVENTION The compounds of this invention have the structure ##SPC1## Where Z is --CH. sub. 2 CH. sub. 2 -- or --CH=CH--; R and R' are H or alkyl having a total of no more than 4 carbons or together RR' is an alkylidene of no more than 4 carbons; X is H or halogen; and m and n individually are 0 or 1
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