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 Optical fibres based on polycarbonate fibres, and a process for the production thereof

Details
Inventors: Ebert, Wolfgang; Haese, Wilfried; Vogelsgesang, Roland; Dhein, Rolf;
Assignee: Bayer Aktiengesellschaft (Leverkusen, DE)
Primary Examiner: Lee; John D.
Assistant Examiner:
Attorney, Agent or Firm: Sprung Horn Kramer & Woods

A process for the production of optical fibers based on aromatic polycarbonates wherein the polycarbonate fibres are coated with a plastic, the improvement which comprises (a) to coat the fiber with an UV irradiation-polymerizable mixture which comprises (A) 25 to 75% by weight, based on the total weight of the polymerizable compounds, of a polyfunctional (meth)acrylic acid derivative of the formula ##STR1## (B) 75 to 25% by weight, based on the total weight of the polymerizable compounds, of a monofunctional (meth)acrylate of the formula ##STR2## (C) 0.1 to 10% by weight, based on the total weight of the polymerizable compounds, of a photoinitiator, and (b) to polymerize this mixture on the fibre by UV irradiation.

DETAILED DESCRIPTION What is claimed is: 1.
In the process for the production of optical fibres based on aromatic polycarbonates wherein the polycarbonate fibres are coated with a plastic, the improvement which comprises (a) to coat the fibre with an UV irradiation-polymerisable mixture which comprises (A) 25 to 75% by weight, based on the total weight of the polymerisable compounds, of a polyfunctional (meth)acrylic acid derivative of the formula ##STR10## in which m is 2, 3 or 4, D is the m-valent radical of an aliphatic or aromatic hydrocarbon, R.
sub.
1 is hydrogen or methyl, Z.
sub.
1, Z.
sub.
2 and Z.
sub.
3, independently of one another, are oxygen, sulphur, the --N(R)-- group (in which R is hydrogen, alkyl, substituted alkyl, aralkyl, substituted aralkyl, aryl or substituted aryl or a divalent radical of the formula ##STR11## in which Z is oxygen, sulphur or the --N(R)-- group, and A is a divalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon or a substituted divalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon, Z.
sub.
4 is oxygen, the divalent radical of the formula (II) or one of the following divalent radicals ##STR12## A.
sub.
1, A.
sub.
2, A.
sub.
3 and A.
sub.
4, independently of one another are a divalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon or a substituted divalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon, n is zero or an integer from 1 to 20.
p, q and r, independently of one another, may adopt the value zero or 1, and l has a numerical value such that the molecular weight of the polyfunctional (meth)acrylic acid derivative of the formula (I) is 450 to 5000, (B) 75 to 25% by weight, based on the total weight of the polymerisable compounds, of a monofunctional (meth)acrylate of the formula ##STR13## in which R.
sub.
2 is hydrogen or methyl, A.
sub.
5 is a divalent radical or a substituted divalent radical of an aliphatic or cycloaliphatic hydrocarbon, Z.
sub



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