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Home Manufacturing Materials Poly-alkyl-vinyl-ether-polyolefin-copolymers

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 Poly(alkyl vinyl ether)polyolefin copolymers

Details
Inventors: Patel, Niranjan; Riffle, Judy S.; McGrath, James E.;
Assignee: Virginia Tech Intellectual Properties, Inc. (Blacksburg, VA)
Primary Examiner: Seccuro; Carman J.
Assistant Examiner:
Attorney, Agent or Firm: Fennelly; Richard P., Morris; Louis A.

A blend of a polyolefin and a poly(alkyl vinyl ether) can be blended at elevated temperature to form a copolymer of the polyolefin and poly(alkyl vinyl ether). The resulting composition is useful as a compatibilizer, as a more water permeable substrate than the polyolefin, and as a photo-degradable material.

DETAILED DESCRIPTION We claim: 1.
A reacted polymer blend of a polyolefin and a poly(alkyl vinyl ether) component which is a block or graft copolymer comprising poly(alkyl vinyl ether and polyoxazoline, said reacted blend being prepared by mixing the polymers at an elevated temperature.
2.
A reacted polymer blend as claimed in claim 1 wherein the poly(alkyl vinyl ether) component comprises a minor amount of the copolymer.
3.
A reacted polymer blend as claimed in claim 2 wherein the minor amount comprises up to about 49% by weight).
4.
A reacted polymer blend as claimed in claim 1 wherein the polyolefin is polypropylene.
5.
A reacted polymer blend as claimed in claim 1 wherein the poly(alkyl vinyl ether) is poly(methyl vinyl ether).
6.
A process of forming the reacted polymer blend of claim 1 which comprises heat blending the polyolefin and the poly(alkyl vinyl ether).




Description:
BACKGROUND OF THE INVENTION Blends of poly(alkyl vinyl ethers) with various polymers, e.
g.
, polystyrene, have been reported J.
Hu et al.
, for example, in Polymer Preprints 29(1), June 1988, pp.
321-322 reported that poly(methyl vinyl ether) was miscible with such polymers as polystyrene, poly(vinyl phenol), phenoxy polymers, and poly(ethylene-co-methacrylic acid) but was immiscible with amorphous polyurethane.
Apparently blends of poly(alkyl vinyl ethers) with polyolefins (e.
g.
, polypropylene, polyethylene) have not been reported nor has reactive processing of such blends been performed.
SUMMARY OF THE INVENTION The instant invention relates to novel poly(alkyl vinyl ether)/polyolefin copolymers and reactive processing of blends of a poly(alkyl vinyl ether) and polyolefin to form them.
DESCRIPTION OF THE DRAWING The Drawings form a portion of the instant application wherein: FIG.
1a and 1b are melting point depression plots of polypropylene and blends of polypropylene and poly(methyl vinyl ether); FIG.
2 is another melting point depression plot analogous to those of FIG.
1a and FIG.
1b and FIG.
3 is a plot of the isothermal crystallization rates for polypropylene and certain polypropylene/poly(ethyl vinyl ether) blends processed under differing conditions



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