Polyurethane composition and laminates made therewith

DETAILED DESCRIPTION What we claim is: 1.
A method of forming a polyester fiberglass laminate that requires a pull in excess of 60 pounds per square inch to separate the polyester fiberglass laminate consisting of spreading an adhesive on the surface of the polyester fiberglass specimen and bringing said specimen into laminating relationship with a second specimen until the adhesive has set, said adhesive consisting essentially of a reaction mixture 1.
of 100 parts of a reactive hydrogen containing polymeric material having a molecular weight of about 700 to 4500 selected from the class consisting of polyester polyols, polyether polyols and polyester amides, 2.
about 38 to 80 parts of an organic polyisocyanate, 3.
at least 5 parts to no more than about 200 parts of an inert powdery filler with the proviso that in no case shall the amount of filler exceed that amount which when mixed with a hundred parts of the reactive hydrogen containing polymeric material renders the resulting mixture unspreadable, 4.
sufficient catalyst to achieve set of the reaction mixture in at least a quarter of an hour at about 75.
degree.
F.
, and 5.
sufficient monomeric nitrogen containing polyol having from 3 to 6 hydroxyls to be about equivalent to the excess polyisocyanate relative to the amount of reactive hydrogen containing polymeric material.
2.
The method of claim 1 wherein the organic polyisocyanate is toluene diisocyanate.
3.
The method of claim 1 wherein the organic polyisocyanate is 4,4'-diisocyanato phenyl-methane.
4.
An adhesive characterized by requiring a pull in excess of 60 pounds per square inch to separate two polyester impregnated fiberglass panels bonded therewith and composed of a reaction mixture 1.
of 100 parts of a reactive hydrogen containing polymeric material having a molecular weight of about 700 to 4500 selected from the class consisting of polyester polyols, polyether polyglycols and polyester amides, 2.
about 38 to 80 parts of an organic polyisocyanate, 3.
at least five parts to no more than about 200 parts of an inert powdery filler with the proviso that in no case shall the amount of filler exceed that amount which when mixed with a hundred parts of the reactive hydrogen containing polymeric material renders the resulting mixture unspreadable, and 4