Process for the production of an aluminum triformate solution containing alkali metal and/or alkaline earth metal, highly concentrated aluminum triformate solutions containing alkali and/or alkaline earth metal, and their use

DETAILED DESCRIPTION The invention claimed is: 1.
A process for the production of a solution comprising aluminum triformate by neutralization of an aqueous aluminate liquor containing aluminum and at least one member selected from the group consisting of alkali metal and alkaline earth metal which comprises: neutralizing the aluminate liquor by introducing the aluminate liquor into formic acid the neutralization being carried out; i) at a temperature of 5.
degree.
C.
to 110.
degree.
C.
when the aluminum content is from 10 to 80 g/l; or ii) at a temperature below 25.
degree.
C.
when the aluminum content is from above 80 to 350 g/l, to form a neutralized mixture containing a precipitated solid, and heating the neutralized mixture containing the precipitate to form a clear aluminum triformate solution.
2.
A process of claim 1 wherein the aluminate liquor is an aqueous solution with an aluminum content of 70 to 200 g/l and a sodium content of 130 to 220 g/l.
3.
A process as claimed in claim 2, wherein the aluminate liquor is an aqueous sodium aluminate liquor with a ratio by weight of sodium oxide to aluminum oxide of 5:1 to 1:5 and preferably 2:1 to 1:2.
4.
A process as claimed in claim 3, wherein neutralization of the aluminate liquor is carried out to a pH value of at most 4.
5.
A process as claimed in claim 4, wherein neutralization of the aluminate liquor is carried out with a molar ratio of aluminum to formic acid of 1:2.
5 to 1:3.
5.
6.
A process as claimed in claim 5, wherein the solid precipitated after neutralization is converted into a clear solution with stirring at a temperature of 50.
degree.
to 80.
degree.
C.
7.
A process as claimed in claim 6, wherein stabilizers selected from the group consisting of ethylenediamine tetraacetic acid, sulfophthalic acid, sulfosalicylic acid, water-soluble salts of these acids, and isopropanol, optionally in admixture with organic solvents or water, are used before, after, or both before and after neutralization.
8.
A process as claimed in claim 1, wherein an aqueous solution of a mixture of aluminum oxide, hydroxide, or both oxide and hydroxide and alkali metal, alkaline earth metal, or both alkali metal and alkaline earth metal oxides, hydroxides, or both oxides and hydroxides with an aluminum content of 10 to 350 g/l and an alkali metal, alkaline earth metal, or both alkali metal and alkaline earth metal content of 10 to 350 g/l is used as the aluminate liquor