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Home Manufacturing Materials Process-for-the-production-of-paper-using-silica-based-sols

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 Process for the production of paper using silica-based sols

Details
Inventors: Greenwood, Peter; teborg, SE), Linsten; Magnus Olof (Kungä, lv, SE); Johansson-Vestin, Hans E.;
Assignee: Akzo Nobel N.V. (Arnhem, NL)
Primary Examiner: Fortuna; José A.
Assistant Examiner:
Attorney, Agent or Firm: Burke; Michelle J., Parker; Lainie E.

The invention relates to an aqueous silica-based sol comprising a nitrogen-containing organic compound and silica-based particles with a specific surface area of at least 300 square meters per gram of silica. The invention further relates to a process for the production of an aqueous silica-based sol comprising a nitrogen-containing organic compound which comprises incorporating a nitrogen-containing organic compound into a silica-based sol containing silica-based particles with a specific surface area of at least 300 square meters per gram of silica. The invention also relates to the use of an aqueous silica-based sol comprising a nitrogen-containing organic compound and silica-based particles with a specific surface area of at least 300 square meters per gram of silica as a flocculating agent in the production of pulp and paper and in water purification. The invention further relates to a process for the production of paper from an aqueous suspension containing cellulosic fibres, and optional fillers, which comprises adding to the suspension (i) an aqueous silica-based sol comprising an organic nitrogen-containing compound and (ii) at least one charged organic polymer, forming and draining the suspension on a wire.

DETAILED DESCRIPTION 1.
A process for the production of paper which comprises: i) providing an aqueous suspension containing cellulosic fibres, and optional fillers; ii) adding to the suspension at least 0.
001% by weight, based on dry cellulosic fibres and optional fillers, of at least one cationic or amphoteric organic polymer and at least 0.
001% by weight, calculated as SO2 and based on dry cellulosic fibres and optional fillers, of an aqueous silica-based sol comprising anionic silica-based particles and an organic nitrogen containing compound having molecular weight less than 1,000; and iii) forming and draining the obtained suspension on a wire.
2.
The process of claim 1, wherein the cationic or amphoteric organic polymer has a molecular weight of at least 1,000,000.
3.
The process of claim 1, wherein the cationic or amphoteric organic polymer is selected from the group consisting of amphoteric starch, cationic starch, amphoteric guar gum, cationic guar gum, amphoteric acrylamide-based polymer, cationic acrylamide-based polymer, cationic poly(diallyl-dimethyl ammonium chloride), cationic polyethylene imines, cationic polyamines, cationic polyamidoamines, cationic vinylamide-based polymers, cationic melamine-formaldehyde, cationic ureaformaldehyde resins, and mixtures thereof.
4.
The process of claim 3, wherein the cationic or amphoteric organic polymer is cationic starch.
5.
The process of claim 3, wherein the cationic or amphoteric organic polymer is a cationic acrylamide-based polymer.
6.
The process of claim 1, wherein the aqueous silica-based sol has a molar ratio of SO2 to N from 1:1 to 50:1.
7.
The process of claim 1, wherein the nitrogen-containing organic compound contains at least one oxygen atom.
8.
The process of claim 1, wherein the nitrogen-containing organic compound is an amine containing from 2 to 12 carbon atoms.
9.
The process of claim 1, wherein the nitrogen-containing organic compound is selected from the group consisting of triethanolamine, diethanolamine, dipropylamine, aminoethylethanolamine, 2-methoxyethylamine, N,N-dimethylethanolamine, choline hydroxide, choline chloride, tetramethylammonium hydroxide, tetramethylammonium hydroxide, tetraethanol ammonium hydroxide, and mixtures thereof



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