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 Self-curing copolymers containing both hydroxyamide functions and carboxy or anhydride functions, and compositions

Details
Inventors: Cenci, Harry J.; Swift, Graham;
Assignee: Rohm and Haas Company (Philadelphia, PA)
Primary Examiner: Kight, III; John
Assistant Examiner:
Attorney, Agent or Firm:

.beta.-Hydroxyalkylamide polymers are disclosed as self-curing by means of carboxy or anhydride functions in said polymers. The polymers are effective in solution, aqueous emulsion and powder coating formulations.

DETAILED DESCRIPTION We claim: 1.
A curable addition polymer containing (a) one or more carboxy groups, salts of said carboxy groups or carboxylic acid anhydride groups and (a) one or more pendant .
beta.
-hydroxyalkyl amide groups of the formula: ##STR10## wherein R.
sup.
3 is H or CH.
sub.
3.
2.
The composition of claim 1 in which the carboxy, salt or anhydride groups are the residues of at least one ethylenically unsaturated acid monomer selected from acrylic, methacrylic, maleic, or itaconic acids and maleic anhydride, the acid monomer and hydroxyamide monomer each being used in the copolymer in the amount of 1% to 20% by weight of the monomers in the copolymer, and the ratio of hydroxyamide functional groups to salt, carboxy, or anhydride functional groups is between about 0.
5 and about 2, wherein one anhydride group is equal to two carboxy functions.
3.
The composition of claim 1 contained in water or an organic liquid selected from aromatic and aliphatic hydrocarbons, dimethyl formamide, ethers, ketones, esters, and alcohols.
4.
The method of curing the composition of claim 1 comprising the step of heating it at a temperature of from 125.
degree.
C.
to 400.
degree.
C.
until the polymer is cured.
5.
The method of curing the composition of claim 2 comprising the step of heating it at a temperature of from 125.
degree.
C.
to 400.
degree.
C.
until the polymer is cured.
6.
The method of curing the composition of claim 3 comprising the step of heating it at a temperature of from 125.
degree.
C.
to 400.
degree.
C.
until the polymer is cured.




Description:
This invention relates to a novel method for curing or crosslinking polymers having carboxy or anhydride groups and .
beta.
-hydroxyalkylamide groups, that is, self-curing polymers containing both carboxy and .
beta.
-hydroxyalkylamide functionality.
Studies show that the .
beta.
-hydroxyalkylamide functions employed in this invention provide efficient self-curing of carboxy or anhydride units contained in the same polymers, and can be employed without any catalyst being required



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