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Smoking compositions containing acylpyrazine ether flavorants
| Details |
Inventors: Williams, David L.; Southwick, Everett W.; Houminer, Yoram;
Assignee: Philip Morris Incorporated (New York, NY)
Primary Examiner: Daus; Donald G.
Assistant Examiner: Teoli, Jr.; William A.
Attorney, Agent or Firm:
In one of its embodiments the present invention provides a smoking composition which contains a novel type of acylpyrazine ether flavorant additive as exemplified by 1-(3-methoxy-2-pyrazinyl)-2-methyl-1-propanone. ##STR1## |
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DETAILED DESCRIPTION What is claimed is: 1.
An acylpyrazine ether corresponding to the formula: ##STR19## where R is a substituent selected from aliphatic, alicyclic and aromatic hydrocarbyl groups having 2-12 carbon atoms, R.
sup.
1 is a substituent selected from hydrogen and alkyl groups having 1-6 carbon atoms, X is etheric oxygen or sulfur, and R.
sup.
2 is a substituent selected from aliphatic, alicyclic and aromatic hydrocarbyl groups having 1-12 carbon atoms, with the proviso that the position-(3) substituent is not hydrogen.
2.
1-(3-Ethylthio-2-pyrazinyl)-1-propanone.
3.
1-(3-Methoxy-2-pyrazinyl)-2-methyl-1-propanone.
4.
1-(3-Furfurylthio-2-pyrazinyl)-2-methyl-1-propanone.
5.
1-[3,6-Dimethyl-5-(cis-hex-3-enoxy)-2-pyrazinyl]-1-propanone.
6.
A halo-acylpyrazine corresponding to the formula: ##STR20## where Y is a halogen atom, R is a substituent selected from aliphatic, alicyclic and aromatic hydrocarbyl groups having 2-12 carbon atoms, and R.
sup.
1 is a substituent selected from hydrogen and alkyl groups having 1-6 carbon atoms, with the proviso that the position-(2) substituent is not hydrogen.
7.
1-(3-Chloro-2-pyrazinyl)-1-propanone.
8.
1-(3-Chloro-2-pyrazinyl)-2-methyl-1-propanone.
9.
1-(5-Chloro-3,6-dimethyl-2-pyrazinyl)-1-propanone.
10.
A halo-acylpyrazine corresponding to the formula: ##STR21## where Y is a chlorine atom, R is a substituent selected from aliphatic, alicylclic and aromatic hydrocarbyl groups having 2-12 carbon atoms, and R.
sup.
1 is a substituent selected from hydrogen and alkyl groups having 1-6 carbon atoms, with the proviso that the position-(2) substituent is not hydrogen.
11.
A halo-acylpyrazine corresponding to the formula: ##STR22## where Y is a bromine atom, R is a substituent selected from aliphatic, alicylclic and aromatic hydrocarbyl groups having 2-12 carbon atoms, and R.
sup.
1 is a substituent selected from hydrogen and alkyl groups having 1-6 carbon atoms, with the proviso that the position-(2) substituent is not hydrogen.
Description:
BACKGROUND OF THE INVENTION Alkylpyrazines are typical of organic compounds which have been recognized as having useful properties for application as flavorants in tobacco and foodstuffs
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Manufacturing Materials 
