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 Stabilized polyketone blend

Details
Inventors: Smutny, Edgar J.;
Assignee: Shell Oil Company (Houston, TX)
Primary Examiner: Nutter; Nathan M.
Assistant Examiner:
Attorney, Agent or Firm:

Polymer compositions comprising an intimate mixture of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and finely divided cellulose demonstrate improved melt stability and retained apparent crystallinity.

DETAILED DESCRIPTION What is claimed is: 1.
A composition stabilized against loss of apparent crystallinity when subjected to melting and crystallization cycles which comprises a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon having incorporated therein a stabilizing quantity of a finely divided cellulose.
2.
The composition of claim 1 wherein the polymer is of the repeating formula --CO--CH.
sub.
2 --CH.
sub.
2).
sub.
x [CO--G)].
sub.
y wherein G is a moiety of an ethylenically unsaturated hydrocarbon of at least 3 carbon atoms, polymerized through the ethylenic unsaturation, and the ratio of y:x is no more than about 0.
5.
3.
The composition of claim 2 wherein the cellulose has a particle size from about 10 microns to about 30 microns.
4.
The composition of claim 3 wherein the cellulose is present in a quantity of from about 0.
005% by weight to about 20% by weight, based on total composition.
5.
The composition of claim 4 wherein y is O.
6.
The composition of claim 4 wherein the ratio of y:x is from 0.
01 to about 0.
1.
7.
The composition of claim 6 wherein G is a moiety of propylene.
8.
A method of stabilizing a linear alternating polymer of carbon monxoide and at least one ethylenically unsaturated hydrocarbon against loss of apparent crystallinity upon being subjected to melting and crystallization by incorporating therein a stabilizing quantity of a finely divided cellulose.
9.
The method of claim 8 wherein the polymer is of the repeating formula --CO--CH.
sub.
2 --CH.
sub.
2).
sub.
x [CO--G)].
sub.
y wherein G is a moiety of an ethylenically unsaturated hydrocarbon of at least 3 carbon atoms polymerized through the ethylenic unsaturation, and the ratio of y:x is no more than about 0.
5.
10.
The method of claim 9 wherein the cellulose has a particle size of from about 10 microns to about 30 microns.
11.
The method of claim 10 wherein the quantity of cellulose is from about 0.
005% by weight to about 20% by weight, based on total composition.
12.
The method of claim 11 wherein y is 0



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