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Details
Inventors: Manning, James H.; Hutten, Irwin M.;
Assignee: James River Corporation of Virginia (Richmond, VA)
Primary Examiner: Chin; Peter
Assistant Examiner:
Attorney, Agent or Firm:

A method for the production of a fibrous web having textile length fibers wherein a fiber furnish is formed by dispersion of the fibers in an unfoamed carrier medium of water and an associative thickener of ethylene oxide base urethane block copolymers or hydroxyethylcellulose ethers having a C.sub.10 to C.sub.24 alkyl side chain in an amount within the range of from about 1 to about 150 pounds of thickener per ton of dry fiber and including an anionic viscosity modifier in the range of 10 to 500 ppm. The furnish having a consistency in the range of 0.05 to 0.2 weight percent fibers is supplied to a high speed papermaking machine for forming a fibrous web. The textile length fibers may be polyester fibers being 1.5 denier and 3/4 inches. The high speed papermaking machine may be a twin-wire papermaking machine or a suction breast roll papermaking machine or a crescent former papermaking machine.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The term "polymeric surfactant" is defined as a molecule which contained a plurality, two or more, of both hydrophilic moieties and hydrophobic moieties.
This definition is derived from that of a simple surfactant, surface reactant agent, comprising a hydrophilic moiety and a hydrophobic moiety.
The difference in the hydrophilic and the hydrophobic portions of the polymeric surfactant molecules control the propensity of these molecules to arrange themselves in preferential molecular orientations at the interface between dissimilar substances.
In the case of the present invention, the polymer surfactants attach themselves to the surfaces of fibers at their interface with water as the suspending medium.
The key molecular feature is that the molecules contain both hydrophilic portions and hydrophobic portions.
The key distinction from simple surfactants is that these molecules would contain a multiplicity, two or more, of these types of groups.
The type of groups, as well as the relative positions of these ranges within specific molecules, can include a broad range of chemical moieties and distributions.
The associative thickener molecules have a multiplicity of hydrophobic and hydrophilic portions or "blocks" which form networks in an aqueous carrier medium, the exact nature of which is dependent upon the molecular shape and composition, as well as the nature of the solvent.
The formation of networks provides changes in the rheology of the solution that result in increases in viscosity; hence, the term "associative thickeners.
" Associative thickeners have been used in the paint industry for changing the rheological properties of paint formulations.
The present invention provides an improved method for forming fibrous webs from a water furnish containing textile length fibers which includes polymeric surfactant associative thickeners in the water making up the fiber furnish.
Such polymer surfactant associative thickeners have being developed primarily for use in the formation of latex paints



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