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 Method of manufacturing color picture tubes

Details
Inventors: Matsuzaki, Osamu; Abe, Michio; Mitobe, Koichi; Tanno, Seikichi;
Assignee: Hitachi, Ltd. (Tokyo, JP)
Primary Examiner: Smith; Ronald H.
Assistant Examiner: Bueker; Richard
Attorney, Agent or Firm: Pfund; Charles E.

In a method of manufacturing a color picture tube of the type comprising the steps of coating phosphors of three primary colors on the inner surface of the face plate of the color picture tube to form dots or stripes of the phosphors, applying an acrylic resin emulsion on the dots or stripes of the phosphors to form an acrylic resin film, vapor depositing metal onto the film to form a metallic reflecting film, subjecting the acrylic resin film to a pyrolysis for decomposing it into gases, and removing the gases, the acrylic resin emulsion comprises a plurality of emulsions respectively containing conventional acrylic resin and normal butyl methacrylate resin. The normal butyl methacrylate resin is mixed with the conventional acrylic resin at a ratio of 5 to 40% by weight. According to this method, it is possible to prevent bulging of the metallic reflecting film during baking step while minimizing the number of the pin holes and cracks of the metallic reflecting film so as not to decrease the brightness of the reproduced picture.

DETAILED DESCRIPTION It is an object of this invention to provide an improved method of manufacturing a colour picture tube utilizing an improved film forming method which can prevent bulging of a metallic reflecting film during baking step while minimizing the number of pin holes so as not to decrease the brightness of the reproduced picture.
To attain the above object, this invention takes advantage of the fact that when the number of pin holes in the metallic reflecting film is constant, that is, the gas permeability of the film is constant, the bulge of the metallic reflecting film tends to grow in proportion to the quantity of gases given off by the organic substance of the acrylic resin per unit time, especially, to the peak value of that quantity because a large amount of gases resulting from the pyrolysis is forced to pass through the fixed number of pin holes.
Thus, in this invention, a plurality of acrylic resins having different pyrolysis characteristics are chosen and mixed such that the pyrolysis is carried out with a relatively low peak value.
According to this invention, there is provided a method of manufacturing a colour picture tube of the type comprising the steps of coating phosphors of three primary colours on the inner surface of the face plate of the colour picture tube to form dots or stripes of the phosphors, applying an acrylic resin emulsion on the dots or stripes of the phosphors to form an acrylic resin film, vapour depositing metal onto the film to form a metallic reflecting film, subjecting the acrylic resin film to a pyrolysis for decomposing it into gases, and removing the gases, wherein the acrylic resin emulsion comprises a mixture of a plurality of emulsions containing different acrylic resins having different pyrolysis characteristics.
Preferred acrylic resins are conventional acrylic resin and normal butyl methacrylate resin and the film forming emulsion contains the normal butyl methacrylate resin mixed with the conventional acrylic resin at a ratio of 5 to 40% by weight



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