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1,3-Oxazole phosphates and phosphonates as insecticides and miticides
| Details |
Inventors: Gutman, Arnold D.;
Assignee: Stauffer Chemical Company (Westport, CT)
Primary Examiner: Rush; Raymond V.
Assistant Examiner:
Attorney, Agent or Firm: Ackerman; Joel G.
Compounds having the formula ##STR1## in which R is phenyl, phenylthio, phenoxy, or lower alkylthio; R.sub.1 is lower alkoxy; R.sub.2 is lower alkyl or lower alkoxy; R.sub.3 is lower alkyl; and X is sulfur or oxygen. The compounds have utility as insecticides and miticides. The compounds can be prepared through novel intermediates having the formula ##STR2## BY A NOVEL PROCESS OF REACTING A METHYL KETONE OXIME WITH A HALOACETYL CHLORIDE IN THE ABSENCE OF AN ACID ACCEPTOR. |
|
DETAILED DESCRIPTION What is claimed is: 1.
A compound having the formula ##STR10## in which R is phenyl, phenylthio, phenoxy or lower alkylthio; R.
sub.
1 is lower alkoxy; R.
sub.
2 is lower alkyl or lower alkoxy; R.
sub.
3 is lower alkyl and X is sulfur or oxygen, provided that when R is isopropylthio, R.
sub.
3 is a lower alkyl group containing from 1 to 3 carbon atoms.
2.
A compound according to claim 1 in which X is oxygen.
3.
A compound according to claim 1 in which X is sulfur.
4.
A compound according to claim 1 in which R is lower alkylthio and R.
sub.
2 is lower alkyl.
5.
A compound according to claim 4 in which Y is sulfur.
6.
A compound according to claim 1 in which R is lower alkylthio and R.
sub.
2 is lower alkoxy.
7.
A compound according to claim 6 in which X is sulfur.
8.
A compound according to claim 1 in which R is phenyl, R.
sub.
1 is ethoxy; R.
sub.
2 is ethoxy; R.
sub.
3 is methyl and X is sulfur.
9.
A compound according to claim 1 in which R is phenyl, R.
sub.
1 is ethoxy, R.
sub.
2 is ethyl, R.
sub.
3 is ethyl and X is sulfur.
10.
A compound according to claim 1 in which R is phenyl, R.
sub.
1 is methoxy, R.
sub.
2 is methoxy, R.
sub.
3 is methyl and X is sulfur.
11.
A compound according to claim 1 in which R is methylthio, R.
sub.
1 is ethoxy, R.
sub.
2 is ethoxy, R.
sub.
3 is methyl and X is sulfur.
12.
A compound according to claim 1 in which R is methylthio, R.
sub.
1 is ethoxy, R.
sub.
2 is ethyl, R.
sub.
3 is methyl and X is sulfur.
13.
A compound according to claim 1 in which R is methylthio, R.
sub.
1 is methoxy, R.
sub.
2 is methoxy, R.
sub.
3 is methyl and X is sulfur.
14.
A compound according to claim 1 in which R is phenylthio, R.
sub.
1 is ethoxy, R.
sub.
2 is ethoxy, R.
sub.
3 is methyl and X is sulfur.
15.
A compound according to claim 1 in which R is isopropylthio, R.
sub.
1 is ethoxy, R.
sub.
2 is ethoxy, R.
sub.
3 is methyl and X is sulfur.
16.
A compound according to claim 1 in which R is isopropylthio, R.
sub.
1 is methoxy, R.
sub.
2 is methoxy, R.
sub.
3 is methyl and X is sulfur.
17.
A compound according to claim 1 in which R is isopropylthio, R
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