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 Aqueous alkaline composition

Details
Inventors: Lenoir, Pierre Marie;
Assignee: The Dow Chemical Company (Midland, MI)
Primary Examiner: Hertzog; Ardith
Assistant Examiner: Delcotto; Gregory R.
Attorney, Agent or Firm:

The aqueous composition comprises a non-ionic surfactant and an alkali metal hydroxide. The non-ionic surfactant is a propylene oxide-ethylene oxide derivative of an alcohol of formula I R--O--?C.sub.2 H.sub.3 (CH.sub.3)O!.sub.a --?C.sub.2 H.sub.4 O!.sub.b --H(I ) and/or a butylene oxide-ethylene oxide derivative of an alcohol (ROH), of formula II R--O--?C.sub.2 H.sub.3 (C.sub.2 H.sub.5)O!.sub.c --(C.sub.2 H.sub.4 O!.sub.b --H (II) wherein R is a linear or branched alkyl or alkenyl group containing from 4 to 11 carbon atoms, a (the average degree of propoxylation per mole) is from 2.5 to 7, b (the average degree of ethoxylation per mole) is from 1 to 10, and c (the average degree of butoxylation per mole) is from 0.5 to 4. The content of the alkali metal hydroxide is at least 5 percent, based on the total weight of the aqueous composition. The aqueous alkaline solution is useful for cleaning the surface of articles, such as fruit, vegetables or containers for food, or for chemical peeling of fruit or vegetables, metal working or cotton mercerization.

DETAILED DESCRIPTION OF THE INVENTION In Formula I a is from 2.
5 to 7, preferably from 3 to 6.
5, more preferably from 3.
5 to 6, most preferably, a is higher than b.
In Formula II c is from 0.
5 to 4, preferably from 1 to 3, more preferably from 1 to 2.
In Formulas I and II b is from 1 to 10, preferably from 1 to 9, more preferably from 2 to 7, most preferably from 3 to 6.
R is a linear or branched-alkyl or alkenyl group containing from 4 to 11, preferably from 6 to 10, more preferably from 7 to 9 carbon atoms, such as the butyl, butenyl, pentyl, pentenyl, hexyl, hexenyl, heptyl, heptenyl, octyl, octenyl, nonyl, nonenyl, decyl, decenyl, undecyl or undecenyl.
The group R may be branched which is for example the case in 1-methyl-propyl, 2-methyl-propyl, tert-butyl, isopentyl, 2-methyl-butyl, tert-pentyl, isohexyl, isoheptyl, isooctyl, etc.
The group R may be unsaturated which is, for example, the case in 2-butenyl, 3-butenyl, etc.
However, the group R preferably is a linear alkyl group containing the above-mentioned ranges of carbon atoms.
The most preferred group R is the linear octyl group.
R and b in Formula I can be the same or different from R and b in Formula II.
The compounds of Formula I and/or II can be utilized in combination with other non-ionic or ionic surfactants.
Propylene oxide-ethylene oxide derivatives of alcohols are generally known.
They can be produced in a known manner by reacting alcohols first with propylene oxide and then with ethylene oxide.
The published German patent application 41 15 149 discloses an alkoxylation of fatty alcohols wherein 1 to 20 mols of ethylene oxide and/or propylene oxide are reacted with one mol of a fatty alcohol containing 6 to 24 carbon atoms.
U.
S.
Pat.
No.
4,965,014 discloses a liquid non-ionic surfactant mixture comprising compounds of formula R--O--(PO).
sub.
1-2 --(EO).
sub.
6-8 --H, wherein PO is the residue of a ring-opened propylene oxide, EO is the residue of a ring-opened ethylene oxide and R is a mixture of alkyl or alkenyl moieties of a specific distribution wherein 75 to 90 percent of the alkyl or alkenyl moieties contain 9 or 10 carbon atoms



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