DETAILED DESCRIPTION OF THE INVENTION The instant invention pertains to a composition for coating glass which is the reaction product of two components. The first component is a trialkoxysilyl adduct which may be linear or branched; the second component is a polysiloxanediol or silanediol. The first component is a compound of formula A [(EO). sub. 3 -Si-R-X-]. sub. k T (A) wherein k is 2 to 4, E is methyl or ethyl, R is ethylene or trimethylene, X is --NHCONH--, --NHCOO--, --S--, --NHCO-- or a direct bond, where the --NH-- group is attached to R, and T is, when k is 2 and X is a direct bond, --NHCONH--, or T is, when X is --NHCONH--, the residue of a diisocyanate or a triisocyanate after removal of 2 or 3 NCO groups, or T is, when X is --NHCOO--, the residue of a diol, triol or tetraol or of a isocyanate or a poly(dimethylsiloxane) alkanepolyol after removal of 2, 3 or 4 OH groups, or T is, when X is --S--, alkylene of 1 to 12 carbon atoms, alkanetriyl of 3 to 8 carbon atoms or alkanetetrayl of 4 to 10 carbon atoms, or T is, when X is --NHCO--, alkylene of 2 to 10 carbon atoms or arylene of 6 to 10 carbon atoms. The second component needed to prepare the instant coating composition is a compound of the formula B HO-[Si(L). sub. 2 -O-]. sub. n -H (B) wherein n is 1 to 100, and L is methyl, isopropyl, --CH. sub. 2 CH. sub. 2 CF. sub. 3, tert-butyl, cyclohexyl or phenyl. Preferably n is 1 and L is phenyl. The reaction of the first and second components forms a compound of formula [HO[Si(L). sub. 2 -O-]. sub. n -Si(OE). sub. 2 R-X-]. sub. k T (I) where L, R, X, T, n and k are as defined above. Preferably, k is 2 or 3, most preferably 2. Preferably E is ethyl. Preferably R is trimethylene. Preferably X is --NHCONH-- or --NHCOO--, most preferably --NHCONH--. Preferably when X is --NHCONH--, T is a residue of a diisocyanate. Preferably when X is --NHCOO--, T is the residue of a diol. Preferably when X is --S--, T is alkylene of 1 to 8 carbon atoms, most preferably alkylene of 2 to 4 carbon atoms. Preferably X is --NHCO--, T is alkylene of 2 to 8 carbon atoms, most preferably alkylene of 4 to 6 carbon atoms
|