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 Glass composition for alkali-resistant glass fiber

Details
Inventors: Iizawa, Yoshihiro;
Assignee: Ikebukuro Horo Kogyo Co., Ltd. (JP)
Primary Examiner: Vertiz; O. R.
Assistant Examiner: Bell; Mark
Attorney, Agent or Firm: Wenderoth, Lind & Ponack

This invention relates to a glass composition for alkali-resistant glass fiber, which comprises: (a) 30 - 57% by weight of SiO.sub.2 ; (b) 12 - 26% by weight of ZrO.sub.2 ; (c) 14 - 26% by weight of R.sub.2 O (wherein R represents Na, K or Li); (d) 1 - 11% by weight of R'O (wherein R' represents Ca, Ba, Mg, Zn or Co); (e) 0.1 - 6% by weight of CaF.sub.2 ; (f) 0.1 - 10% by weight of M.sub.2 (SiF.sub.6) (wherein M represents Na, K or Li); and (g) 0.1 - 12% by weight of B.sub.2 O.sub.3. This invention further relates to a glass composition for alkali-resistant glass fiber, which comprises: (a) 30 - 57% by weight of SiO.sub.2 ; (b) 12 - 25% by weight of ZrO.sub.2 ; (c) 14 - 26% by weight of R.sub.2 O (wherein R represents Na, K or Li); (d) 1 - 11% by weight of R'O (wherein R' represents Ca, Ba, Mg, Zn or Co); (e) 0.1 - 6% by weight of CaF.sub.2 ; (f) 0.1 - 10% by weight of M.sub.2 (SiF.sub.6) (wherein M represents Na, K or Li); (g) 0.1 - 12% by weight of B.sub.2 O.sub.3 ; (h) an effective amount of up to 3% by weight of TiO.sub.2 ; (i) an effective amount of up to 3% by weight of Al.sub.2 O.sub.3 ; and (j) an effective amount of up to 3% by weight of Fe.sub.2 O.sub.3.

DETAILED DESCRIPTION What I claim is: 1.
A glass composition for alkali-resistant glass fiber, said composition having a glass liquification temperature of 750.
degree.
-900.
degree.
C.
, which comprises: (a) 30-48% by weight of SiO.
sub.
2 ; (b) 12-26% by weight of ZrO.
sub.
2 ; (c) 14-26% by weight of R.
sub.
2 O (wherein R represents Na, K or Li); (d) 1-11% by weight of R'O (wherein R' represents Ca, Ba, Mg, Zn or Co); (e) 1-5% by weight of CaF.
sub.
2 ; (f) 0.
1-10% by weight of M.
sub.
2 (SiF.
sub.
6) (wherein M represents Na, K or Li); and (g) 0.
1-12% by weight of B.
sub.
2 O.
sub.
3.
2.
A glass composition for alkali-resistant glass fiber according to claim 1, which additionally contains an effective amount of up to 3% by weight of TiO.
sub.
2, an effective amount of up to 3% by weight of Al.
sub.
2 O.
sub.
3 and an effective amount of up to 3% by weight of Fe.
sub.
2 O.
sub.
3.
3.
A glass composition according to claim 1 wherein the CaF.
sub.
2 is present at 1.
6 to 5% by weight.
4.
A glass composition according to claim 2 wherein the CaF.
sub.
2 is present at 1.
6 to 5% by weight.




Description:
DETAILED EXPLANATION OF THE INVENTION This invention relates to a glass composition.
More particularly, this invention relates to a glass composition for glass fiber used in a cement product as a reinforcing material.
It is well known that glass fiber used as a reinforcing material for cement must be alkali-resistant, and that zirconium oxide is an effective ingredient to impart alkali-resistant properties to glass.
The well known ZrO.
sub.
2 -containing alkali-resistant glass contains 10-25% by weight of ZrO.
sub.
2.
However, the conventional ZrO.
sub.
2 -containing alkali-resistant glass composition has disadvantages is that the fiberizing temperature or glass liquefaction temperature is very high, e.
g.
1100.
degree.
C.
-1300.
degree.
C.
, due to the presence of the ZrO.
sub.
2, and that the viscosity of molten glass at high temperature is very high.
The present invention provides a glass composition for alkali-resistant glass fiber having a high alkali-resistance as well as a low melting point, without the above mentioned disadvantages of the prior arts



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