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Home Molecular Biology Novel-cationic-lactam-polymers-and-1-3-alkyl-amino-propyl-pyrrolidone-2-intermediates-therefor

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Details
Inventors: O'Lenick, Jr., Anthony J.;
Assignee: LCE Partnership (Lake Geneva, WI)
Primary Examiner: Springer; David B.
Assistant Examiner:
Attorney, Agent or Firm:

The present invention deals with novel quaternary polymeric compounds and their application as softening, anti-tangle, and conditioning agents. The polymers conform to the following structure: ##STR1## R is selected from CH.sub.3 --(CH.sub.2).sub.b --; CH3--(CH2).sub.c --(CH.dbd.CH)--(CH.sub.2).sub.d ; CH.sub.3 --(CH.sub.2).sub.e --CH(CH.sub.3)--(CH.sub.2).sub.f --; CH.sub.3 --(CH.sub.2).sub.b --O--R.sup.1 --(CH.sub.2).sub.3 --; CH.sub.3 --(CH.sub.2).sub.d --CH(CH.sub.3)--(CH.sub.2).sub.e --O--R.sup.1 --(CH.sub.2).sub.3 -- and ##STR2## R.sup.1 is --(CH.sub.2 CH.sub.2 --O).sub.x --(CH.sub.2 CH(CH.sub.3)--O).sub.y --(CH.sub.2 CH.sub.2 O).sub.z --; x y and z are independently integers from 0 to 20; b,c,d,e are independently integers from 5 to 20; m and n are independently integers from 4 to 20; a is an integer from 2 to 2,000; Y is an anionic counter ion needed for charge balance and is selected from chloride, bromide, sulfate, and phosphate.

DETAILED DESCRIPTION What is claimed is: 1.
A polymeric quaternary compound conforming to the following formula; ##STR20## R is selected from CH.
sub.
3 --(CH.
sub.
2).
sub.
b --; CH3--(CH.
sub.
2).
sub.
c --(CH.
dbd.
CH)--(CH.
sub.
2).
sub.
d ; CH.
sub.
3 --(CH.
sub.
2).
sub.
e --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
f --; CH.
sub.
3 --(CH.
sub.
2).
sub.
b --O--R.
sup.
1 --(CH.
sub.
2).
sub.
3 --; CH.
sub.
3 --(CH.
sub.
2).
sub.
d --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
e --O--R.
sup.
1 --(CH.
sub.
2).
sub.
3 -- and ##STR21## R.
sup.
1 is --(CH.
sub.
2 CH.
sub.
2 --O).
sub.
x --(CH.
sub.
2 CH(CH.
sub.
3)--O).
sub.
y --(CH.
sub.
2 CH.
sub.
2 --O).
sub.
z --; x y and z are independently integers from 0 to 20; b,c,d,e are indenpendently integers from 5 to 20; m and n are independently integers from 4 to 20; a is an integer from 2 to 125; Q is an anionic counter ion needed for charge balance and is selected from chloride, bromide, sulfate, and phosphate.
2.
A compound of claim 1 wherein R is CH.
sub.
3 --(CH.
sub.
2).
sub.
b --.
3.
A compound of claim 1 wherein R is CH3--(CH2).
sub.
c --(CH.
dbd.
CH)--(CH.
sub.
2).
sub.
d --.
4.
A compound of claim 1 wherein R is CH.
sub.
3 --(CH.
sub.
2).
sub.
e --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
f --.
5.
A compound of claim 1 wherein R is CH.
sub.
3 --(CH.
sub.
2).
sub.
b --O--R--.
sup.
1 (CH.
sub.
2).
sub.
3 --.
6.
A compound of claim 1 wherein R is CH.
sub.
3 --(CH.
sub.
2).
sub.
d --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
e --O--R.
sup.
1 --(CH.
sub.
2).
sub.
3 --.
7.
A compound of claim 1 wherein R is ##STR22## 8.
A compound of claim 1 wherein x y and z are each 0.
9.
A compound of claim 1 wherein Q is chloride.
10.
A substituted lactam intermediate conforming to the following formula; ##STR23## R is selected from CH.
sub.
3 --(CH.
sub.
2).
sub.
b --; CH3--(CH2).
sub.
c --(CH.
dbd.
CH)--(CH.
sub.
2).
sub.
d ; CH.
sub.
3 --(CH.
sub.
2).
sub.
e --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
f --; CH.
sub.
3 --(CH.
sub.
2).
sub.
b --O--R.
sup.
1 --(CH.
sub.
2).
sub.
3 --; CH.
sub.
3 --(CH.
sub.
2).
sub.
d --CH(CH.
sub.
3)--(CH.
sub.
2).
sub.
e --O--R.
sup.
1 --(CH.
sub.
2).
sub.
3 -- and ##STR24## R.
sup.
1 is --(CH.
sub.
2 CH.
sub.
2 --O).
sub.
x --(CH.
sub.
2 CH(CH.
sub



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