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Partial esters of epoxy containing compounds
| Details |
Inventors: Hirshman, Justin L.; Garcia, Dana S.; Kazemizadeh, Mohammad R.;
Assignee: Elf Atochem North America, Inc. (Philadelphia, PA)
Primary Examiner: Dees; Jose G.
Assistant Examiner:
Attorney, Agent or Firm: Marcus; Stanley A.
The present invention relates to a partial ester derived from the reaction product of an oxirane containing acid or derivative thereof, and a reactive hydroxyl compound selected from the group consisting of diols, triols, di-diols and 1,4-dihydroxy butane and a halogen containing polymer compositon thereof. The oxirane compound can be derived from the group consisting of epoxidized vegetable oil, epoxidized fish oil, an aliphatic or arylaliphatic containing craboxyl compound having an oxirane group in the aliphatic chain. |
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DETAILED DESCRIPTION What is claimed is: 1.
A partially esterified polyhydroxyl containing compound derived from the reaction of: an oxirane compound selected from the group consisting of epoxidized vegetable oil and ester derivatives thereof, epoxidized fish oil and ester derivatives thereof, and an aliphatic or arylaliphatic carboxyl group containing compound having at least one oxirane group in the aliphatic chain where the aliphatic chain has at least four carbons; a polyhydroxyl containing compound selected from the group consisting of aliphatic diols, triols, di-diols and 1,4-dihydroxy butane based compound; wherein the partially esterified polyhydroxyl compound exhibits a thermal change between 135.
degree.
C.
and 200.
degree.
C.
as measured by Thermal Gravimetric Analysis.
2.
The compound as recited in claim 1 wherein: the diol is selected from a 1,2-dihydroxy alkane compound and a 1,4-dihydroxy butane compound; the triol has at least one primary and one adjacent, secondary hydroxyl; the di-diols consist of two primary and adjacent secondary hydroxyl pairs separated by from two to four methylene groups; and the oxirane compound contains at least 12 but no more than 28 carbons.
3.
The compound as recited in claim wherein the polyhydroxyl containing compound is selected from the group consisting of aliphatic diols and 1,4-hydroxyl butane.
4.
The compound as recited in claim 1 wherein the polyhydroxyl containing compound is selected from the group consisting of aliphatic triols and di-diols.
5.
The compound as recited in claim 4 wherein the triol is glycerol 6.
The compound as recited in claim 1 wherein the reaction is conducted under substantially anhydrous conditions.
7.
The compound as recited in claim 1 having an oxirane content of at least three weight percent.
8.
A partially esterified compound derived from the anhydrous transesterification or transalcoholysis reaction of: an oxirane compound selected from the group consisting of epoxidized vegetable oil, epoxidized fish oil, and epoxidized compounds having the formula ##STR13## wherein, y=2 to 24, n=1-2 ##STR14## m=0 to 2 z=1 to 23 ##STR15## s=1-3 R
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Molecular Biology 
