DETAILED DESCRIPTION We claim: 1. An azo compound of the formula: ##STR343## wherein D is an unsubstituted anthraquinone radical or an anthraquinone radical substituted by one or more substituents selected form the group consisting of chlorine, bromine, NHCOCH. sub. 3, CH. sub. 3, NHCOC. sub. 6 H. sub. 5 or NHCOC. sub. 6 H. sub. 4 Cl; or D is a amino phthalimide radical of the formula: ##STR344## or D is the radical of a tetraazo component H. sub. 2 N--D--NH. sub. 2 having the formulae: ##STR345## Y. sup. 5 is hydrogen, chlorine, bromine, methyl or cyano; and Y. sup. 6 is hydrogen, phenyl, benzoylamino, or phenyl or benzoylamino which are substituted by nitro; wherein Z is a direct bond, SO. sub. 2, NH, CO, SO. sub. 2 NH, CONH, NHCONH, or NHCOCONH and the rings B are unsubstituted or substituted by chlorine, bromine, methyl, nitro, or methoxy; wherein said radical D is free from complex-forming hydroxyl and carboxyl groups; n is one or two; R is hydrogen or a phenyl, naphthyl or pyridyl radical which may be substituted by chlorine, bromine, nitro, methyl, methoxy or ethoxy; X is hydroxyl, alkyl or a carboxylic acid alkyl ester having an alkyl ester radical selected from the group consisting of C. sub. 1 -C. sub. 6 alkyl or alkoxyalkyl, phenyl and benzyl; or X is phenyl, naphthyl or pyridyl which is unsubstituted or substituted by chlorine, bromine, nitro, methyl, methoxy or ethoxy; or X is acylamino selected from the group consisting of NHCOCH. sub. 3, NHCOC. sub. 2 H. sub. 5, NHCOC. sub. 3 H. sub. 7, NHCOC. sub. 6 H. sub. 5, NHCOC. sub. 6 H. sub. 4 Cl, NHCOC. sub. 6 H. sub. 3 Cl. sub. 2, NHCOC. sub. 6 H. sub. 4 Br, NHCOC. sub. 6 H. sub. 4 OCH. sub. 3, NHCOC. sub. 10 H. sub. 7, NHCONH. sub. 2, NHCONHC. sub. 6 H. sub. 5, ##STR346## and the ring A is a substituted or unsubstituted, with a proviso that said ring A is free from SO. sub. 3 H groups. 2. An azo compound of the formula: ##STR347## where D is an aminoanthraquinone radical of the formula: ##STR348## or D is an aminophthalimide radical of the formula: ##STR349## or D is the radical of a tetrazo component H
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