Home | Links | Contact Us | More About Intellectual Property | Bookmark
Search patents:
Home Molecular Biology Process-and-catalyst-for-olefin-polymerization

 Process and catalyst for olefin polymerization

Details
Inventors: Martin, Joel L.;
Assignee: Phillips Petroleum Company (Bartlesville, OK)
Primary Examiner:
Assistant Examiner:
Attorney, Agent or Firm:

Solid olefin polymerization catalysts are prepared by forming a solution of an organophosphate or organophosphoramide and certain metal halides and then reacting the solution with a halogenated transition metal compound to form a solid.

DETAILED DESCRIPTION OF THE INVENTION The organophosphates and organophosphoramides contemplated for use in the present invention are those which are capable of causing the metal halide to go into solution.
Typical organophosphates would include those of the formula (RO).
sub.
3 PO wherein each R can be the same of different hydrocarbyl radical containing 1 to 10 carbon atoms.
Typical representative examples of such compounds include tri-n-butyl phosphate, triethyl phosphate, triphenyl phosphate, and the like and mixtures.
The currently preferred phosphates are those wherein each R is an alkyl radical containing 1 to 6 carbon atoms.
Typical organophosphoramide would include those of the formula (R.
sub.
2 N).
sub.
3 PO.
Representative examples of such compounds include hexamethylphosphoramide, hexaethylphosphoramide, and the like and mixtures.
The metal halides include the chlorides, bromides, and iodides of the specified metals.
They are preferably used in a substantially anhydrous form.
Representative examples of such metal halides include magnesium dichloride, magnesium diiodide, magnesium dibromide, manganese dichloride, lanthanum trichloride, cerium trichloride, praseodymium trichloride, samarium trichloride, erbium trichloride, gadolinium trichloride, neodymium trichloride, dysprosium trichloride and the like.
The liquid employed for forming the solution should be dry, i.
e.
substantially free of water.
Typically the liquid is an organic liquid which is liquid at normal room temperatures, viz.
50.
degree.
F.
to 90.
degree.
F.
Typical liquids include, for example, normally liquid hydrocarbons having 3 to 12 carbon atoms per molecule, such as n-pentane, n-heptane, methylcyclohexane, toluene, xylenes, and the like.
The currently preferred liquids are aliphatic hydrocarbons containing 4 to 8 carbon atoms per molecule.
The amount of organophosphate or organophosphoramide needed to cause the dissolution of the metal halide can vary depending upon the metal halide selected and the desired level of dissolution of the metal halide



Related patents
  Polymers of N,N-disubstituted acrylamides and method for the preparation thereof
What is claimed is: 1. A block copolymer, the block copolymer being of the configuration AB or ABA, the block A being a polymer of N-methyl, N-phenyl acrylamide and B is ...
  Derivatives of 5-hydroxy-6-diloweralkylaminomethyl-benzofurans
We claim: 1. A compound of the formula: ##SPC5## wherein R is lower alkyl, R' is selected from the group consisting of lower alkyl and phenyl, R.sup.2 is lower alkyl, R....
  Process for producing parasiticidal milbemycin derivatives by culturing streptomyces
We claim: 1. A process for the production of a compound of formula (I) ##STR10## wherein R.sup.1 is hydrogen or methyl, R.sup.2 is hydrogen or E 2-methyl 2-butenoyloxy, ...
  Hypocholesterolemic fermentation products
What is claimed is: 1. A compound of structural formula I in substantially pure form: ##STR6## 2. An antihypercholesterolemic pharmaceutical composition comprising a ...
  Contact lens disinfecting and preserving solution
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows: 1. A method for preserving or disinfecting soft contact ...

0.014

Archive: All patents - Links

Copyright (c)2006 Eipa-patents.org - All rights reserved